A 5.00 ml sample of white vinegar is diluted in acetone and analyzed by GC-TCD using 1-propanol as internal standard and a ZB-Wax20 M Column. The most retained component in the analysis is: O a. Methanol Ob. Acetic Acid Oc Formic Acid Od. Acetone Oe 1-propanol
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- The concentration of purified OXA-M290 is tested with a BCA assay. Serial dilutions of a bovine serum albumin (BSA) stock solution are prepared, then pipetted into a 96-well plate; each dilution of the BSA standard is tested in triplicate. Then, bicinchoninic acid and Cu2+ ions are added to all of the wells of the plate. After incubating the plate for 1 hour, a microplate reader is used to measure the absorbance of all of the wells in the plate at 560 nm. This generates the following data: BSA conc. (μg/mL), Replicate 1 Absorbance, Replicate 2 Absorbance, Replicate 3 Absorbance 40, 1.360, 1.403, 1.481 20, 0.750, 0.745, 0.810 10, 0.380, 0.344, 0.398 5, 0.198, 0.160, 0.183 2.5, 0.090, 0.100, 0.085 1.25, 0.038, 0.043, 0.051 0.625, 0.024, 0.028, 0.019 Prepare a calibration curve using these data. You can use Excel, R, SPSS or an equivalent graphing software. In this graph, plot absorbance (y-axis) against the concentration of the protein standard (x-axis). Calculate and plot…A brewed tea brand sample was subjected to solvent extraction to extract caffeine. The cup of tea measuring 200 mL was extracted with petroleum ether. With KD = 20.0 (caffeine in pet ether-water), the % caffeine (194.10) extracted after 3 extractions with a total of 75.0 mL pet ether used is: A. 97.7% B. 28.6% C. 71.4% D. 2.33%Hexanoic acid was added to an immiscible biphasic solvent system, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D2) of hexanoic acid in water with respect to CCl4.
- Hexanoic acid was added to an immiscible biphasic solvent sysem, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D1) of hexanoic acid in CCl4 with respect to water.(i) An unknown sample (0.100 g dissolved in 100 mL ethanol) was then analysed by GC, among a number of otherpeaks, there was one at 9.5 min with integration 1250. Discuss how this could be quickly confirmed as being due to A. (ii) An aliquot (1 mL) of a solution of B (0.100 g dissolved in 100 mL ethanol) was added to the unknown sample. Now in addition to the peak at 9.5 min (integration 1250) there was a peak at 11.5 (integration 1000). Determine how much A was in the unknown sample.A 5.00-mL sample of blood was treated with trichloroacetic acid to precipitate proteins. After centrifugation, the resulting solution was brought to pH 3 and extracted with two 5-mL portions of methyl isobutyl ketone containing the lead-complexing agent APCD. The extract was aspirated directly into an air/acetylene flame and yielded an absorbance of 0.527 at 283.3 nm. Five-milliliter aliquots of standard solutions containing 0.400 and 0.600 ppm of lead were treated in the same way and yielded absorbances of 0.396 and 0.599. Find the concentration of lead in the sample in ppm assuming that Beer’s law is followed.
- A 5.00-mL sample of blood was treated with trichloroacetic acid to precipitate proteins. After centrifugation, the resulting solution was brought to pH 3 and extracted with two 5-mL portions of methyl isobutyl ketone containing the lead-complexing agent APCD. The extract was aspirated directly into an air/acetylene flame and yielded an absorbance of 0.569 at 283.3 nm. Five-milliliter aliquots of standard solutions containing 0.400 and 0.600 ppm of lead were treated in the same way and yielded absorbances of 0.396 and 0.599. Please calculate the concentration of lead in the sample in ppm.A 18 g of unknown organic sample was dissolve in 756 mL of benzene. The boiling point of benzene was increased by 3.36oC. As the first step of analysis, determine the moecular weight of the unknow sample? Kb of benzene= 2.64oC/m Bb of benzene = 80.09 oC density of benzene = 0.874 g/mL at 25 °C Answer in whole number, no units required.I have set up my spreadsheet using this sample data and reproduced the result with a pKa of 4.64. true or false
- Pesticide residues were found in a lot of oranges; the compound identified was the epoxide of heptachlor (EH). To quantify the amount of this pesticide in oranges, 20 grams were taken from fruit peels and mixed with methylene chloride to extract it. The concentration of heptachlor epoxide in the sample was determined by gas chromatography coupled to a detector mass (GC-MS); and calibration was performed using anthracene (A) as internal standard. For In this analysis, the anthracene had a concentration of 350 ppm and the same volume was added to each standard. The table below shows the concentrations of the standard and the ratio of the areas.and the sample is: 0.1080.Determine the concentration of heptachlor epoxide in the sample.Study the tabulated data during an gravimetric analysis of BaSO4 experiment Trial T1 T2 T3 Mass of sample (g) 1.0040 1.0100 1.0050 Constant weight of empty crucible (g) 10.2453 10.2454 10.2454 Constant weight after ignition (g) 10.3253 10.3252 10.3253 1. Calculate the mean mass of precipitate as BaSO4 a. 0.0799 g b. 0.0800 c. 0.08 g 2. Calculate the mean weight of sulphate (MM BaSO4 = 233.39 g/mol, So42- = 176 g/mol)? a. 0.0603 g b. 0.06 g c. 0.06025 g 3. Calculate the mean % SO42- in the sample a. 6.00% b. 5.991% c. 5.9908%A scientist wishes to measure the concentration of methyl benzoate in a plant stream by gas chromatography. He prepares a sample of butyl benzoate to use as an internal standard. The results of a preliminary run, which used a solution known to contain 1.37 mg/mL of methyl benzoate (peak A) and 1.51 mg/mL of butyl benzoate (peak B), are shown. The area of peak A is determined to be 3.40×102 and the area of peak B is determined to be 398 measured in arbitrary units by the computer. To measure the sample, 1.00 mL of a standard sample of butyl benzoate containing 2.49 mg/mL is mixed with 1.00 mL of the plant stream material. Analysis of the mixture gave a peak area of 437 for peak A and 415 for peak B. What is the concentration of methyl benzoate in the plant stream?