A ceric sulfate solution that was standardized using 200 mg of arsenic trioxide (MW = 197.84g/n) consuming 38.5ml of the solution. The solution was the used to assay 2,000 mg sample of Ferous Carbonate (FeCO3 = 115.85 g/n). In the titration, the analyte consumed 34.2 ml of the standard solution. Compute for the %P of FeCO3. Round off answers to two decimal places.
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- 1. 1093-g sample of impure Na2CO3 was analyzed by residual precipitimetry. After adding 50.00 mL of 0.06911 M AgNO3, the sample was back-titrated with 0.05781 M KSCN, requiring 27.36 mL to reach the endpoint. The percentage Na2CO3 (MW = 106.0 g/mole) in the tested sample is ________ % ? Note: Express final answer using least number of significant figures. 2. The alkalinity of natural waters is usually controlled by OH- (MW = 17.01 g/mole), CO3-2 (MW = 60.01 g/mole), and HCO3- (MW = 61.01 g/mole), which may be present singularly or in combination. Titrating a 10.0-mL sample to a phenolphthalein endpoint requires 38.12 mL of a 0.5812 M solution of HCl, and an additional 18.67 mL of the same titrant to reach the methyl orange endpoint. The composition of the sample is _________% CO3-2 and ___________ % OH- Note: Express final answers using least number of significant figures.If 500mL of 0.10M Ca2+ is mixed with 500mL of 0.10M SO42-, what mass of calcium sulfate will precipitate? Ksp for CaSO4 is 2.40 • 10-5. express answer to 3 significant figures. And include units.A commercial vinegar was analyzed by titration to determine the percent acetic acid. Briefly, 10.00 mL of vinegar sample was diluted to 100. mL solution in volumetric flask. A 25.00 mL aliquot from the diluted vinegar required 25.55 mL of 0.1005 M NaOH to reach the phenolphthalein endpoint. Which is the correct equation between the analyte and titrant reaction? CH3COOH + NaOH → NaCH3COO + H2O 2CH3COOH + NaOH → NaCH3COO + H2O C20H14O4 + NaOH → NaC20H14O4 + H2O CH3COOH + 2NaOH → NaCH3COO + H2O
- Solid cobalt (II) acetate is slowly added to 125 mL of 0.0945 M ammonium chromate solution. What is the concentration of cobalt required to just initiate precipitation? The Ksp of CoCrO4 is 7.1 * 10 -4. Report answer in scientific notation to two sig figs.30mL 0.9% v/v green food coloring. Transfer 2mL of of food coloring to flask, QS the flask to 100mL with DI water. What is the concentration of the standard?a) What mass of Fe(NH4)2(SO4)2•2H2O(s) is required to prepare a 500 mL solution containing 100 ppm (m:v) in Fe? b) Using this stock solution, what aliquot must be used to prepare calibration solutions, 100 mL volume, of the following concentrations: 0.100 ppm, 0.500 ppm, 2.00 ppm, 4.00 ppm, and 7.00 ppm.
- PS. Further values required for the solvings are give in the various situations below. (ANSWER) Situation: A community in a mountainous area of Bohol uses water collected from a nearby natural spring. A sample was submitted to a laboratory for the analysis of its total hardness. Required: SHOW YOUR COMPLETE CALCULATIONS. BASED ON THE IMAGE PROVIDED BELOW FOR THIS QUESTION: Calculate the amount of titrant used in each trial to reach endpoint. Report total hardness of the sample as mean ±sd. a. 250.0 mL of 500.0 ppm of CaCO3 solution from a primary standard (assume solvent is distilled water only). Answer : Mass of CaCO3 = 0.125 g b, The EDTA solution was standardized by titrating it with a 25.0 mL aliquot of the CaCO3 solution. How much of the titrant was consumed. Answer: Volume of EDTA consumed = 12.405 g c. Calculate the average titer (mg CaCO3/mL EDTA). Mass of CaCO3 in 25 mL CaCO3 solution: 0.0125 g Answer: 1.008 mg CaCO3/ mL EDTAThe thiourea (NH2)2CS in a 1.600 g sample of an unknown organic material was extracted into a dilute acid solution and was titrated with 42.50 mL of 0.0010 M Hg2+. Equation: 4 (NH2)2CS + Hg2+ → [(NH2)2CS]4Hg2+ Find the percentage thiourea present in the sample.Five drops of dichlorofluorescein have been added to a solution containing 0.800 g sample which required 25.30 mL of 0.100 M AgNO3. (c) Calculate the weight percent NaCl in the original sample.
- A local company sent you their green alternative for window cleaner to be tested for percent (w/v) acetic acid content. For your experiment, you first standardized your NaOH titrant with 0.8053 g of (99.80 % purity) KHP. You used 40.60 mL of NaOH for your standardization. After that you then analyzed a 10.00 mL sample and found that you needed 43.20 mL NaOH to reach the end point. Summary of results: Standardization Sample analysis KHP Weight (g) 0.8053 g Volume of sample 50.00 mL Purity 99.80% NaOH (mL) used 33.20 mL NaOH (mL) used 40.60 mL Determine the following: Molarity of NaOH % (w/v) acetic acidA sample weighing 10.91 g containing an unknown amount of H3PO4 was diluted with water and titrated with a standardized concentration of 0.7255 M NaOH. The endpoint was reached after 27.03 mL of the titrant was added. What is the % H3PO4 (97.994 g/mole) in the sample? H3PO4 + 2 NaOH --> Na2HPO4 + 2H2O ROUND OFF FINAL ANSWER TO FOUR (4) SIG FIGSThe thiourea in a 1.455 g sample of organic material was extracted into a dilute sulfuric acid solution and titrated with 37.31 mL of 0.009372 M Hg2+ via reaction: 4(NH2)2CS + Hg2+ →[(NH2)2CS]4 Hg2+ P.S. Answer only the last two letters of the following questions. (Only C and D) a. Is this an example of total analysis technique or concentration technique? Explain. b. Calculate the percent (NH2)2CS ( 76.12 g/mol) in the sample. c. What is classification of the analysis based on the amount of sample and amount of analytes present? Explain. d. If the true value is 10.00%, calculate the absolute and relative error.