(a) A supplement tablet containing about 300.00 mg of calcium ion was dissolved, filtered, and diluted to 100.00 mL volume. Several 2.00 ml samples of the total solution were titrated with 0.0100 M EDTA solution. The mean corrected titration volume was 13.65 mL. Calculate the calcium content of the supplement tablet in mg units. (b) A sample of Epsom Salt of mass 0.7567 g was dissolved uniformly in distilled water in a 250.00 mL volumetric flask. Portions of the magnesium ion solution of volume 10.00 mL were titrated using a 0.01000 M solution of EDTA. The mean corrected titration volume was 12.25 ml. Calculate the percentage by mass (% w / w) of the magnesium in the Epsom Salt sample. (c) A 100.00 mL sample of tap water was titrated with O.0100 M EDTA solution. The mean corrected titration volume was 14.80 mL. Determine the total hardness in ppm of calcium carbonate.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter13: Titrations In Analytical Chemistry
Section: Chapter Questions
Problem 13.5QAP
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Complexometric titrations are generally conducted to determine divalent cations. The most
important applications are the titration of calcium and magnesium with EDTA.
(a)
A supplement tablet containing about 300.00 mg of calcium ion was dissolved, filtered,
and diluted to 100.00 ml volume. Several 2.00 ml samples of the total solution were
titrated with 0.0100 M EDTA solution. The mean corrected titration volume was 13.65
mL. Calculate the calcium content of the supplement tablet in mg units.
(b)
A sample of Epsom Salt of mass 0.7567 g was dissolved uniformly in distilled water in
a 250.00 mL volumetric flask. Portions of the magnesium ion solution of volume 10.00
mL were titrated using a 0.01000 M solution of EDTA. The mean corrected titration
volume was 12.25 ml. Calculate the percentage by mass (% w / w) of the magnesium
in the Epsom Salt sample.
(c)
A 100.00 mL sample of tap water was titrated with 0.0100 M EDTA solution. The mean
corrected titration volume was 14.80 mL. Determine the total hardness in ppm of
calcium carbonate.
Transcribed Image Text:Complexometric titrations are generally conducted to determine divalent cations. The most important applications are the titration of calcium and magnesium with EDTA. (a) A supplement tablet containing about 300.00 mg of calcium ion was dissolved, filtered, and diluted to 100.00 ml volume. Several 2.00 ml samples of the total solution were titrated with 0.0100 M EDTA solution. The mean corrected titration volume was 13.65 mL. Calculate the calcium content of the supplement tablet in mg units. (b) A sample of Epsom Salt of mass 0.7567 g was dissolved uniformly in distilled water in a 250.00 mL volumetric flask. Portions of the magnesium ion solution of volume 10.00 mL were titrated using a 0.01000 M solution of EDTA. The mean corrected titration volume was 12.25 ml. Calculate the percentage by mass (% w / w) of the magnesium in the Epsom Salt sample. (c) A 100.00 mL sample of tap water was titrated with 0.0100 M EDTA solution. The mean corrected titration volume was 14.80 mL. Determine the total hardness in ppm of calcium carbonate.
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