3.Answer ALL parts a) - c).i)State the selection rule for an IR active transition. What factorinfluences the intensity of an IR band?ii) With the aid of a diagram, describe the bonding between a CO ligandand a d-block transition metal ion.iii)Explain why [V(CO)6]- has a lower CO stretching frequency than[Mn(CO)]*.iv) Briefly discuss the influence that binding mode (terminal vs bridging) hason the stretching frequency of CO in coordination complexes.c) A single analysis using chromatography produced a chromatogram with threepeaks. The peak for compound A has a retention time of 0.44 min, compoundB of 5.86 min and compound C of 6.14 min.i)Compound A does not interact at all with the stationary phase. Whatinformation can be obtained from the retention time of A?ii)Calculate the retention factors for compounds B and C respectively.iii)Calculate the selectivity factor for compounds B and C.iv)The peaks for compounds B and C have respective widths of 0.32 minand 0.35 min. Calculate the resolution of compounds B and C, andcomment on the significance of the magnitude of your answer.v) The peak for compound C has a Full Width Half Maximum (FWHM) of0.14 min. Calculate the number of theoretical plates for compound C.vi) Given that compound C is analysed using a column of length 20 m,calculate the Height Equivalent of Theoretical Plates (HETP).a)

According to bartleby guidelines, we're supposed to answer first three subparts of a multipart…

a) Answer ALL parts a) - c). i) State the selection rule for an IR active transition. What factor influences the intensity of an IR band? ii) With the aid of a diagram, describe the bonding between a CO ligand and a d-block transition metal ion. iii) Explain why [V(CO)6]- has a lower CO stretching frequency than [Mn(CO)]*. iv) Briefly discuss the influence that binding mode (terminal vs bridging) has on the stretching frequency of CO in coordination complexes.

a) Answer ALL parts a) - c). i) State the selection rule for an IR active transition. What factor influences the intensity of an IR band? ii) With the aid of a diagram, describe the bonding between a CO ligand and a d-block transition metal ion. iii) Explain why [V(CO)6]- has a lower CO stretching frequency than [Mn(CO)]*. iv) Briefly discuss the influence that binding mode (terminal vs bridging) has on the stretching frequency of CO in coordination complexes.

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.30QAP

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