A chemist examined a sample containing a mixture of inorganic salts, and the following observations were recorded. Solid + Solid + Salt solution Test dilute HCl(ag) concentrated H2SO4(ag) + BaCl2(ag) Formation of white precipitate insoluble in Observation Effervescence Reddish-brown fumes dilute HCl(aq) *Based on the observations he made, which of the following anion radicals does the sample contain? a) CO32-, NO,", and SO,- b) HCO;", NO>", and SO,2- c) HCO3", NO3", and PO,- d) CO-, NO,-, and PO4-
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- While working in a metal processing facility, Letlen had accidentally mixed two metal vatstogether creating an alloy. One vat was labeled for cadmium, while the other was not. It canbe assumed that these are of pure metal composition. To identify this metal, Letlen took 1.000 g of the homogenous alloy sample composed ofcadmium and the unknown metal, dissolved, and diluted it to exactly 100.0 mL in avolumetric flask. A 20.00-mL aliquot was taken and titrated this using 22.82 mL of 0.05000M EDTA. In a second 20.00-mL aliquot, the Cd was masked through the addition of HCN/NaCN buffer.The titration of the unknown metal in the aliquot required 15.13 mL of EDTA.MW: Cd (112.411 g/mol) a. Calculate the moles of Cd and the moles of unknown metal in the 20.00-mL aliquot.b. Calculate the moles of Cd and the moles of unknown metal in the sample.As part of the analysis of water samples, the hardness of water is commonly measured and calculated. It is commonly expressed in ppm by mass (parts per million) of CaCO3. Parts per million is also equivalent to milligrams of CACO3 per liter of water. In a sample taken by an environmentalist, he was able to observe a hardness count of 205 mg CacO3/L. Given this hardness count of the sample, what is the molar concentration of Ca2+ ions in the water sample?As part of a soil analysis on a plot of land, a scientist wants to determine the ammonium content using gravimetric analysis with sodium tetraphenylborate, Na+B(C6H5)4−. Unfortunately, the amount of potassium, which also precipitates with sodium tetraphenylborate, is non‑negligible and must be accounted for in the analysis. Assume that all potassium in the soil is present as K2CO3 and all ammonium is present as NH4Cl. A 5.095 g soil sample was dissolved to give 0.500 L of solution. A 150.0 mL aliquot was acidified and excess sodium tetraphenylborate was added to precipitate both K+ and NH4+ ions completely. B(C6H5)4-+K+⟶KB(C6H5)4(s) B(C6H5)4-+NH4+⟶NH4B(C6H5)4(s) The resulting precipitate amounted to 0.269 g. A new 300.0 mL aliquot of the original solution was made alkaline and heated to remove all of the NH4+ as NH3. The resulting solution was then acidified, and excess sodium tetraphenylborate was added to give 0.129 g of precipitate. Find the mass percentages of NH4Cl and…
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- What is the maximum solid solubility of Mg in Al? At what temperature does it occur? e. An Al-Mg alloy (10 wt% Mg, 90 wt% Al) is heated slowly (to insure equilibrium) from a temperature of 200 C: i. At what temperature does the first liquid phase form? ii. What is the composition of the liquid phase at the temperature in part i.? iii. At what temperature does complete melting (no solid phase remaining) occur? iv. What is the composition of the last solid remaining prior to complete melting? f. Using the equilibrium phase diagram of Figure 1, identify the phases present, their compositions, and their relative mass fractions at equilibrium for a 70 wt% Mg – 30 wt% Al alloy held at 300 C.Will Mn(OH)2 precipitate from a 0.01 M solution of MnCl2 at pH = 9? Ksp(Mn(OH)2) = 1,0 x 10-13. Discuss from solubility diagrams and prove by calculation.calculation. Co is a metal that is present in every lithium battery to stabilize its charge and toincrease stability. Every cell phone, tablet and electric car relies on the availability ofcobalt, 97% of which is extracted from mines in places like the Congo, where essentially slave labor is used.Cobalt ions form complexes with e.g. CN- . You see solubility diagrams and fraction diagrams for CoCO3 with and without the addition of 10 mM CN- .. Explain whythe solubility of cobalt carbonate increases at high pH when cyanide ions are present.Write reaction formulas for the formation of the dominant cobalt cyanide complexes.We have a mixture of 100 mL of Fe3+ solution (1.00 × 10–3 M) and 100 mL of A- ion solution (1.00 × 10–3 M). The mixture has a deep blue color, indicating the formation of a complex between Fe3+ and A-. From spectrophotometric analysis, we find that 30.0% of the Fe3+ is in the form of a complex, where there are two probable formulae: FeX2+ or FeX3. a. Balance the following equations and calculate the concentrations of the remaining species. b. After reaching equilibrium states, write the equilibrium expressions and the equilibrium constants for both cases in (a).