(a) For refractory ceramic materials, cite two characteristics that improve with and two characteristics that are adversely affected by increasing porosity.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter22: Inorganic Materials
Section: Chapter Questions
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Question Seven
(a) For refractory ceramic materials, cite two characteristics that improve with and two characteristics
that are adversely affected by increasing porosity.
(b) Show that the minimum cation-to-anion radius ratio for a coordination number of 4 is 0.225.
(Hint: Use the AX crystal structure, assuming the anion spheres touch in plane).
(c) The unit cell for Al>O; has hexagonal symmetry with lattice parameters a = 0.4759 nm and c 1.2
nm. If the density of this material is equal to 3.99 g/cm' and is calculated according to the formuka
n'(EAc+ EA)
VcNA
Calculate the atormic packing factor for Al>O1, given that the ionic radius for AI is 0.053 nm and i
0' is 0.140 nm. Take N = 6.023 x 1023 atoms'mole.
(d) Mention any three industrial ceramics and indicate their applications.
Transcribed Image Text:Question Seven (a) For refractory ceramic materials, cite two characteristics that improve with and two characteristics that are adversely affected by increasing porosity. (b) Show that the minimum cation-to-anion radius ratio for a coordination number of 4 is 0.225. (Hint: Use the AX crystal structure, assuming the anion spheres touch in plane). (c) The unit cell for Al>O; has hexagonal symmetry with lattice parameters a = 0.4759 nm and c 1.2 nm. If the density of this material is equal to 3.99 g/cm' and is calculated according to the formuka n'(EAc+ EA) VcNA Calculate the atormic packing factor for Al>O1, given that the ionic radius for AI is 0.053 nm and i 0' is 0.140 nm. Take N = 6.023 x 1023 atoms'mole. (d) Mention any three industrial ceramics and indicate their applications.
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