A nickel compound containing peroxide (abbreviated as Ni2O2) can donate oxygen atoms to other molecules. A model for such a reaction is the conversion of cyclooctene to 1,2-cyclooctene oxide. Three experiments were run at different concentrations and the initial rates determined. Experiment [Cyclooctene] (mM) [Ni2O2] (mM) Initial Rate (mM/s) 1 4.80 4.00 3.46 ×× 10–3 2 9.60 4.00 6.91 ×× 10–3 3 9.60 2.00 3.46 ×× 10–3

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Chapter13: Rates Of Reaction
Section: Chapter Questions
Problem 13.55QP: Chlorine dioxide, ClO2, is a reddish-yellow gas that is soluble in water. In basic solution it gives...
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A nickel compound containing peroxide (abbreviated as Ni2O2) can donate oxygen atoms to other molecules. A model for such a reaction is the conversion of cyclooctene to 1,2-cyclooctene oxide.

Three experiments were run at different concentrations and the initial rates determined.

Experiment [Cyclooctene]
(mM)
[Ni2O2]
(mM)
Initial Rate
(mM/s)
1 4.80 4.00 3.46 ×× 10–3
2 9.60 4.00 6.91 ×× 10–3
3 9.60 2.00 3.46 ×× 10–3

The rate law will take the form:

Rate = k[Cyclooctene]m[Ni2​O2​]n

What are the values of m and n?

What is the value of the rate constant for the reaction?

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