1. The rate of the homogeneous gas-phase reaction: A + 3B → 2X + Y has been studied. Some of the data are:Initial total pressure change rate(-dP/dt) / (torr/s)Initial pressure AP/ torr352289Initial pressure BP/ torrRun1533923.446.558.1434247617(a) What are the orders of the reaction with respect to A and with respect to B?(b) Assume that the gas mixture is ideal and find the relation between the usual rate of reaction, v, and dP/dt, where P isthe total pressure. The volume is constant.

Order of reaction is defined as the sum of the power of each concentration term in rate law…

Initial pressure A P/ torr 352 Initial pressure B P/ torr 153 Initial total pressure change rate (-dP/dt) / (torr/s) Run 3.44 6.55 3 4 289 247 392 617 8.14 (a) What are the orders of the reaction with respect to A and with respect to B? (b) Assume that the gas mixture is ideal and find the relation between the usual rate of reaction, v, and dP/dt, where P is the total pressure. The volume is constant.

Initial pressure A P/ torr 352 Initial pressure B P/ torr 153 Initial total pressure change rate (-dP/dt) / (torr/s) Run 3.44 6.55 3 4 289 247 392 617 8.14 (a) What are the orders of the reaction with respect to A and with respect to B? (b) Assume that the gas mixture is ideal and find the relation between the usual rate of reaction, v, and dP/dt, where P is the total pressure. The volume is constant.

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 11.50PAE

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