A particular form of cinnabar (HgS) adopts the zinc blendestructure. The length of the unit cell edge is 5.852 Å.(a) Calculate the density of HgS in this form. (b) The mineraltiemannite (HgSe) also forms a solid phase with the zincblende structure. The length of the unit cell edge in thismineral is 6.085 Å. What accounts for the larger unit celllength in tiemmanite? (c) Which of the two substances hasthe higher density? How do you account for the differencein densities?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter22: Inorganic Materials
Section: Chapter Questions
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A particular form of cinnabar (HgS) adopts the zinc blende
structure. The length of the unit cell edge is 5.852 Å.
(a) Calculate the density of HgS in this form. (b) The mineral
tiemannite (HgSe) also forms a solid phase with the zinc
blende structure. The length of the unit cell edge in this
mineral is 6.085 Å. What accounts for the larger unit cell
length in tiemmanite? (c) Which of the two substances has
the higher density? How do you account for the difference
in densities?

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