Q: ОН Pi-delocalization A Present B) Absent
A: Delocalization refers to the spreading of pi-electrons or charge over more than one atom.…
Q: H. D- -Br a) NaCEN H- -H- CH2CH3 I DMSO H. D- H- NaCEN Br- H- b) CH,CH3 DMSO
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Q: HyC. CH3 こof CHy B. 1. homo fopiìe 2. enantiotopic 3. unrelated d. diastereotopic
A: Given compounds,
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A: According to IUPAC the priority order should be: Hydrogen<Alkane<Alkyne<Alkene
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A: We assign R & S using CIP rule: The four atoms or groups attached to the chiral carbon are…
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A: 10. We have to carry out the following transformation (a) and (b).
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A: The name for the given structures has to be given.
Q: 1. 104 2. SO,2- 3
A: Solution - 1. IO4- With IO4- add an additional valence electron to your total because of the…
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A: The given reactions are some of the well established reactions exhibited by carbonyl functionality.
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A: Scheme 1: Step 1: Alcohol oxidation. Step 2: Grignard addition to ketone. Scheme 2: Step 1:…
Q: of -1? CH3 CH3 :F: .. H3C-C-CH3 H-N-CH3 :F-B-F : CH3 :F: H3c.CH3 H (a) (b) (c) (d) (e) HI
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Q: An organie Compound Meduces Fentinge The prominent peale ca are observed in buuture's (A) llution…
A: mass spectroscopy
Q: P ph3 R-CH2-0H >R_CH2-X + Ph + HCX3 X = l or Br write ave mechanis m?
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Q: 17 ČH2CECH A CHz CEC CHz
A: Reagents are the chemicals that we add to bring about a specific change to an organic molecule. Any…
Q: (а) (b) CH2CH3 (с) CH3CH2CHCH=CHČCI CH3OČCH,CH,ČOCH3 NH2 H3C (d) (е) (f) CH2CH2COCHCH3 ČH3…
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Q: O b only
A: Answer- b only
Q: a) b) c) d) OH | CH3CH₂C=0 CH3CH₂CH₂OH Н OH CHOLL CH3CH₂C=0 Cr₂O72- H₂SO4 CH3CH₂C=0 O O || ||…
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Q: KSP ds-
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Q: Draw the products of each reaction, and indicate the stereochemistry where appropriate.
A: (a) In the given reaction, a strong bulky base abstract a proton from alpha position then removal of…
Q: `NH H*
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Q: CH3 CI CH3 H20 (а) CH3 H20 (b) CH3-CH- -ċ-CH3 Br H20 Specify E and Z products (с) Нeat
A: E1 mechanism involves two steps. In first, slow step carbocation intermediate is formed. In second…
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A: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done…
Q: Caiven the following réaction and Kevalue: Acg + Begn= 20Ceg) Ke=4.5X10° Caleulate the value of Ke…
A: Given: The equilibrium constant = 4.5 × 103
Q: ANSWER: Benedict's CH3-CH2 C-HJoluion a. CH3-CH2- CH2-Ċ- H H2 Mi b. Tallen's c CHs - Ct- Ċ - CH3…
A:
Q: Classify each addition as either syn or anti. Br Br₂ Rxn I CH3 Me HBr Rxn II Et Rxn II anti syn anti…
A: If the species add on same side then it is called as syn addition. If the species add on opposite…
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A: Stereoisomers are isomers that share the same composition but differ in how those parts are arranged…
Q: A) -R
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Q: CH hyperconjugation A Present B Absent
A: The alkene functional group is identified by the presence of a double between the two adjacent…
Q: Label attached C–C double bond as E or Z.
A: The E isomer has the two higher priority groups on the opposite sides. The Z isomer has the two…
Q: Match each of the following compounds to one of the HNMR spectra shown below.
A: In a given question , we have to find out compound from the given 1H- NMR spectra
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Q: comylete Machion Waiti its mechaniom also the KNH Ph3 C A
A: There are number of functional group associated with organic compounds which impart specific…
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A: We have been given the observed optical rotation of sample and the specific rotation and the path…
Q: पीजबाश चौ०ह ैनेल्परनपकच्छ Hवे उ्चेकेट एoin्य मुफव न्ठe खट्यऊी fottowing Nog , C०- १०५३ वलव स्eCCN )
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Q: Identify A and B NO2 CH3 A: CH3COCI & Anhy.AIC13 B: Conc.HNO3 & Conc.H2SO4 A: CH3CI & Anhy.AICI3 B:…
A:
Q: Label attached C–C double bond as E or Z.
A: This compound is E alkene.
Q: Draw the organic products formed in each reaction.
A: Carboxylic acid reacts with alcohol in the presence of acid to produce ester. Boc anhydride reacts…
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A: We have to draw resonance of the starting materials as follows in step 2:
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A: We have to tell the products formed on the given reactions.
Q: 5) A. Showt B. Draw f H H. но он a-D-Fru
A: Anomers are cyclic monosaccharides or glycosides that have difference in configuration either at C-1…
Q: B-H
A: Aromatic compounds are those which follows (4n+2) π huckel rule. If n = 0, 2π n = 1,.…
Q: 1. Show the precursors a. b. CN CN
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Q: I have a solution of a standard reference molecule and its' enantiomer. I used 25 mg of the mixture…
A: Given : Mass of mixture = 25mg Specific rotation of the reference material = 100o Observed rotation…
Q: following localizec lоса
A: In the given compound label all lone pair electron and pi bond electron
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A: Given : We have to write the IUPAC nomenclature for the given compounds.
Q: Me e -N Me - N molecule A moleule 3 Ph * Draw a curved -arrow mehanism moleule C trom molecule (…
A:
Q: ny possible stereocenter
A: Stereocentre is defined as a centre which has four different substitutents attached to it.
Q: 4. Why do we have to keep Fehling's A separate with Fehling's B?
A: The question is based on the concept of qualitative analysis. We have to explain the reason for…
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- Estimate the probability of finding an electron which is excited into the 2s orbital of the H atom, looking in a cubical box of volume 0.751036m3 centered at the nucleus. Then estimate the probability of finding the electron if you move the volume searched to a distance of 105.8 pm from the nucleus in the positive z direction. (Note that since these volumes are small, it does not matter whether the volume searched is cubical or spherical.)For the Li atom, the energy difference between the ground state and the first excited state, in which the outermost electron is in a 2p orbital, is 2.961019J . In the Li2+ ion, the energy difference between the 2s and 2p levels is less than 0.00002 of this value. Explain this observation.Consider the representations of the p and d atomic orbitals in Figs. 2-15 and 2- 17. What do the + and signs indicate?
- Explain why the wave model for radiation cannot account for the photoelectric effect.Using Table 5.2, write down the mathematical expression for the 2px wave function for an electronically excited H atom. Estimate the probability of finding the 2px electron if you look in a cubical box of volume of 0.8(pm)3 centered at a distance of 0.5001010m in the =/2 , =0 direction. Does this probability change as you change ? At what angles is the probability of finding the electron smallest and at what angles is the probability the largest? (Note that =2 is the same location as =0 , so don’t double count.)Identify the element that corresponds to each of the simplified photoelectron spectral data given below. (Energy data taken from D. A. Shirley, R. L. Martin, S. P. Kowalczyk. F. R. McFeely, and L Ley: Core-electron binding energies of the first thirty elements Physical Review B, Vol. 15, pp. 544-552, 1977.) (a) There are peaks at energies corresponding to 1079, 70.8, 38.0, 5.14 eV, corresponding to 2, 2, 6, and 1 electrons, respectively. (b) There are peaks at energies corresponding to 4043, 443, 351, 48.4, 30.1, and 6.11 eV, corresponding to 2, 2, 6, 2, 6, and 2 electrons, respectively. (c) There are peaks at energies corresponding to 5475, 638, 524, 77, 47, 12. and 7.3 eV, corresponding to 2, 2, 6, 2, 6, 3, and 2 electrons, respectively.
- Chapter 3 introduced the concept of a double bond between carbon atoms, represented by C=C , with a length near 1.34 Å. The motion of an electron in such a bond can be treated crudely as motion in a one-dimensional box. Calculate the energy of an electron in each of its three lowest allowed states if it is confined to move in a one-dimensional box of length 1.34 Å. Calculate the wavelength of light necessary to excite the electron from its ground state to the first excited state.Spectroscopic studies of Li also show that Zeff(2p)=1.02 . Estimate the energy of the 2p orbital of Li. Calculate the average distance of the electron from the nucleus in the 2p orbital of Li. Comparing your results with those in Problem 13 shows that the energy values differ by about 50%, whereas the average distances are nearly equal. Explain this observation.Sketch the px and dxz orbitals. Be sure to show and label the coordinates.
- Compare the mass of the electron, me, with a the reduced mass of a hydrogen atom; b the reduced mass of a deuterium atom (deuterium=2H); c the reduced mass of a carbon 12 atom having a +5 charge, that is, C5+. Suggest a conclusion to the trend presented by parts a-c.Using a simple particle-in-a-box model for the multiple bonding in 1,2-butadiene (see Example 4.7) and the n=2 wave function for the weakest bound electron, calculate the probability of finding the electron in an 0.1 interval centered midway between the two inner carbon atoms (that is, the center is at x=2.11 , so this interval is from x1=2.06 to x2=2.16 ). Then calculate the probability of finding the electron in an 0.1 interval centered midway between an end carbon atom and the carbon atom that is double-bonded to it in the Lewis dot structure. (You may calculate the appropriate integrals or estimate the relevant areas under the curve graphically.) Then recalculate the probabilities by approximating the integral as |( x 0)|2x , where x0 is evaluated in the middle of the range from x1 to x2 . Finally, explain why you can’t approximate the integral needed for Problem 37(a) in this way.Q.1(a) What were the important advance (s) as a result of which, idea of an electron orbitmovement was swapped by, the notion of probability of finding electron in an orbital?What name was given to the transformed atomic model? Also explain its variouspostulates.(b) Which quantum numbers revel information about the shape, energy, orientation, andsize of the orbitals? How many orbitals are possible for n=4? Which of these may bedescribed as gerade?(c) The signs of the unsquared wave functions are usually shown in plots of the squaredfunctions. Why do you think this practice exists? Give values of angular nodes andplane of 3p, 4d, 2p, 4f, 4s.(d) Predict the trend in values of slater’s constant of the every first element of each groupof p-block elements.