(a) Rate =k [Alkyl Halide][Base] (b) Process follows inversion in stereochemistry (c) Rate of reactivity follows the trend CH3>1°> 2° >3 (d) Mechanism involves carbocations
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Label the following as: SN1, SN2, E1, E2 reactions. Create examples with drawn mechanisms.
![(a) Rate =k [Alkyl Halide][Base]
(b) Process follows inversion in stereochemistry
(c) Rate of reactivity follows the trend CH3>1°> 2° >3
(d) Mechanism involves carbocations](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9a14a4fe-84d4-4d9d-934f-c00bddb83415%2F4669963f-8901-42ec-8392-99f01d882764%2F65p83_processed.jpeg&w=3840&q=75)
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- Show the curved-arrow mechanism for the first step, and the structure of the cyclic intermediate formed, when cyclopentene in treated with KMnO4 . A Lewis structure for the permanganate ion is provided in the hint. Make sure to show all non‑bonding electron pairs and formal charges where necessary. Omit K+ .Identify the pericyclic reactions in the followingreaction schemes. Give the complete reaction name and indicate the course of the reaction with the aid of the arrow notation.Identify the pericyclic reactions in the followingreaction schemes. Give the complete reactionname and indicate the course of the reaction withthe aid of the arrow notation.
- Identify the pericyclic reactions in the following reaction schemes. Give the complete reaction name and indicate the course of the reaction with the aid of the arrow notation.Following is a balanced equation for bromination of toluene.(a) Using the values for bond dissociation enthalpies given in Appendix 3,calculate ∆H0for this reaction.(b) Propose a pair of chain propagation steps and show that they add up to theobserved reaction.(c) Calculate ∆H0for each chain propagation step.(d) Which propagation step is rate-determininSuggest a detailed mechanism for the reaction below. Represent the product in the most stable conformation and also its stereochemistry (Identify stereogenic centers as R or S)
- Can you assit with confirming product(s), define major/minor, show stereochemistry, if appropriate, and/or if no reaction occursDraw the products of attached reaction carried out under high-dilutionconditions. Indicate the stereochemistry at all stereogenic centersThe image below shows a permitted cycloaddition reaction.?
- Draw the major organic product of each reaction. Indicate the stereochemistry at the stereogenic center. Omit byproducts such as salts. If applicable, expand octets to minimize formal charges.Consider the two alkene additions reactions a. What are the major products for each reaction? b. What is the mechanism for each reaction? c. Which reaction would be faster and why? Use words like “transition-state, intermediate and/or reactant/product stability” in your justification. Draw the reaction coordinate diagram for both to assist in your explanation.For eaach image, predict the MAJOR product(s). Show stereochemistry where applicable and draw out ALL stereoisomers formed (as major products) in each reaction. State the mechanism(s) by which the major product(s) are formed (SN1, SN2, E1, and/or E2). Reagents are NOT present in excess.