A SodaStream "sparkling water" home carbonation system pressurizes a 1L water bottle to a pressure of 4 bar (400 kPa) in order to dissolve CO2 gas into the liquid to produce carbonated water also known as "Fizzy-Water". Small bubbles are injected to promote mass transfer such that we can assume the liquid-gas system is at equilibrium with water at a typical refrigerator temperature of 2 °C = 275 K. Assuming that both CO2 and water are ideal gases and CO2 is minimally soluble in water such that Henry's Law is an appropriate model for behavior, what mass of CO2 is dissolved in a 1L water bottle and what would be the equivalent volume, in liters, of that mass if released at room temperature of T = 298 K and pressure of 4 bar (during pressurization) and at 1 bar (when drinking the water)? Assume solvent MH20 18.015 kg/kmol, Psat@2c = 2 kPa == solute Mco₂ = 44.01 kg/kmol, Rco₂ = 0.1889 kPa m³/kgK, Hco₂ = 510 bar, Hint: The mass fraction and mole fraction of a mixture are related to each other by (where the subscript m is for "mixture"). = Mi mi = Wi mm Ni Mi NmMm Yi Mm

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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A SodaStream "sparkling water" home carbonation system
pressurizes a 1L water bottle to a pressure of 4 bar (400 kPa)
in order to dissolve CO2 gas into the liquid to produce
carbonated water also known as "Fizzy-Water". Small
bubbles are injected to promote mass transfer such that we
can assume the liquid-gas system is at equilibrium with
water at a typical refrigerator temperature of 2 °C = 275 K.
Assuming that both CO2 and water are ideal gases and
CO2 is minimally soluble in water such that Henry's Law
is an appropriate model for behavior, what mass of CO2
is dissolved in a 1L water bottle and what would be the
equivalent volume, in liters, of that mass if released at room
temperature of T = 298 K and pressure of 4 bar (during
pressurization) and at 1 bar (when drinking the water)?
Assume
solvent MH20 18.015 kg/kmol, Psat@2c = 2 kPa
==
solute Mco₂ = 44.01 kg/kmol, Rco₂ = 0.1889 kPa m³/kgK, Hco₂ = 510 bar,
Hint: The mass fraction and mole fraction
of a mixture are related to each other by
(where the subscript m is for "mixture").
=
Mi
mi
=
Wi
mm
Ni Mi
NmMm
Yi Mm
Transcribed Image Text:A SodaStream "sparkling water" home carbonation system pressurizes a 1L water bottle to a pressure of 4 bar (400 kPa) in order to dissolve CO2 gas into the liquid to produce carbonated water also known as "Fizzy-Water". Small bubbles are injected to promote mass transfer such that we can assume the liquid-gas system is at equilibrium with water at a typical refrigerator temperature of 2 °C = 275 K. Assuming that both CO2 and water are ideal gases and CO2 is minimally soluble in water such that Henry's Law is an appropriate model for behavior, what mass of CO2 is dissolved in a 1L water bottle and what would be the equivalent volume, in liters, of that mass if released at room temperature of T = 298 K and pressure of 4 bar (during pressurization) and at 1 bar (when drinking the water)? Assume solvent MH20 18.015 kg/kmol, Psat@2c = 2 kPa == solute Mco₂ = 44.01 kg/kmol, Rco₂ = 0.1889 kPa m³/kgK, Hco₂ = 510 bar, Hint: The mass fraction and mole fraction of a mixture are related to each other by (where the subscript m is for "mixture"). = Mi mi = Wi mm Ni Mi NmMm Yi Mm
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