A standard addition method for the voltammetric determination of Pb2+ involved addition of 5.00 mL of 0.800 x 10-3 M Pb2+ to one of two 25.00 mL aliquots of the sample. Supporting electrolyte and water were then added to each aliquot to give a final volume of 50.00 mL. Calculate the molar concentration of Pb2+ based on the following data Diffusion current of sample only = 78.3 uA A Diffusion current of sample with standard addition = 88.7 uA

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter10: Potentiometry And Redox Titrations
Section: Chapter Questions
Problem 2P
icon
Related questions
Question

A standard addition method for the voltammetric determination of Pb2+ involved addition of 5.00 mL of 0.800 x 10-3 M Pb2+ to one of two 25.00 mL aliquots of the sample. Supporting electrolyte and water were then added to each aliquot to give a final volume of 50.00 mL. Calculate the molar concentration of Pb2+ based on the following data

Diffusion current of sample only = 78.3 uA

A Diffusion current of sample with standard addition = 88.7 uA

Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Recommended textbooks for you
Appl Of Ms Excel In Analytical Chemistry
Appl Of Ms Excel In Analytical Chemistry
Chemistry
ISBN:
9781285686691
Author:
Crouch
Publisher:
Cengage
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Fundamentals Of Analytical Chemistry
Fundamentals Of Analytical Chemistry
Chemistry
ISBN:
9781285640686
Author:
Skoog
Publisher:
Cengage