A tetrahedral site in a closest-packed lattice is formed by fourspheres at the corners of a regular tetrahedron. This is equivalentto placing the spheres at alternate corners of a cube. In such aclosest-packed arrangement, the spheres are in contact, and if thespheres have a radius r, the diagonal of the face of the cube is 2r.The tetrahedral hole is inside the middle of the cube. Find firstthe length of the body diagonal of this cube and then the radiusof the tetrahedral hole.

Chemistry: An Atoms First Approach
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Author:Steven S. Zumdahl, Susan A. Zumdahl
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Chapter9: Liquids And Solids
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Problem 8RQ: Describe, in general, the structures of ionic solids. Compare and contrast the structure of sodium...
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A tetrahedral site in a closest-packed lattice is formed by four
spheres at the corners of a regular tetrahedron. This is equivalent
to placing the spheres at alternate corners of a cube. In such a
closest-packed arrangement, the spheres are in contact, and if the
spheres have a radius r, the diagonal of the face of the cube is 2r.
The tetrahedral hole is inside the middle of the cube. Find first
the length of the body diagonal of this cube and then the radius
of the tetrahedral hole.

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