a.) Based on their ground state electron configurations alone, rank these molecule in order of bond dissociation energy from smallest to greatest:A = N2B = B2C = O2.b.) Based on their ground state electron configurations alone, rank these molecule in order of bond length from smallest to greatest:A = N2B = O2C = NO

a)Bond order of N2, B2 and O2 is determined as follows,

Answered: a.) Based on their ground state…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter6: Quantum Mechanics And Molecular Structure

Section: Chapter Questions

Problem 71AP: The MO of the ground state of a heteronuclear diatomicmoleculeAB is mol=CAA+CBB If a bonding...

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a.) Based on their ground state electron configurations alone, rank these molecule in order of bond dissociation energy from smallest to greatest:
A = N₂
B = B₂
C = O₂.

b.) Based on their ground state electron configurations alone, rank these molecule in order of bond length from smallest to greatest:
A = N₂
B = O₂
C = NO

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

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