Acid can dissociate in solution, which characterized by dissociation constant (Ka). Polyprotic acids can dissociate multiple times, which associated by multiple dissociation constant (Kal, Ka2, Ka3 etc.) CO2 dissolve in water forms carbonic acid H2CO3 CO2 (aq) = H2CO3 (aq) K-1.7x103 H2CO3 (aq) = HCO3 (aq) +H'(aq) Kal-2.5x104 HCO3 (aq) = CO3 (aq) + H Ka2 5.0x10-11 (aq) (a) For soda water, the CO2 concentration is 6g/L and the pH is 4. Calculate the equilibrium molar concentration of HCO; and CO32- (b) It is known that the CO2 concentration in air is 387ppm, and the CO2 Henry constant KH= 29.4 atm/mol. The second dissociation is negligible. Calculate the pH of the pure water after equilibrium in air 啟用

Pushing Electrons
4th Edition
ISBN:9781133951889
Author:Weeks, Daniel P.
Publisher:Weeks, Daniel P.
Chapter3: Mechanisms
Section: Chapter Questions
Problem 31EQ: The reaction just described is reversible. Deprotonation of the conjugate acid of an organic base by...
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Acid can dissociate in solution, which characterized by dissociation constant (Ka).
Polyprotic acids can dissociate multiple times, which associated by multiple
dissociation constant (Kal, Ka2, Ka3 etc.)
CO2 dissolve in water forms carbonic acid H2CO3
CO2 (aq) = H2CO3 (aq)
K-1.7x10-
H2CO3 (aq)
= HCO3
+H (aq)
Kal-2.5x104
(aq)
HCO3 (aq) = CO3 (aq) + H" (ag)
Ka2- 5.0x10 ||
(a) For soda water, the CO2 concentration is 6g/L and the pH is 4. Calculate the
equilibrium molar concentration of HCO3 and CO32-
(b) It is known that the CO2 concentration in air is 387ppm, and the CO2 Henry
constant KH= 29.4 atm/mol. The second dissociation is negligible.
Calculate the pH of the pure water after equilibrium in air
ER Windows
BE R Windows-
Transcribed Image Text:Acid can dissociate in solution, which characterized by dissociation constant (Ka). Polyprotic acids can dissociate multiple times, which associated by multiple dissociation constant (Kal, Ka2, Ka3 etc.) CO2 dissolve in water forms carbonic acid H2CO3 CO2 (aq) = H2CO3 (aq) K-1.7x10- H2CO3 (aq) = HCO3 +H (aq) Kal-2.5x104 (aq) HCO3 (aq) = CO3 (aq) + H" (ag) Ka2- 5.0x10 || (a) For soda water, the CO2 concentration is 6g/L and the pH is 4. Calculate the equilibrium molar concentration of HCO3 and CO32- (b) It is known that the CO2 concentration in air is 387ppm, and the CO2 Henry constant KH= 29.4 atm/mol. The second dissociation is negligible. Calculate the pH of the pure water after equilibrium in air ER Windows BE R Windows-
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