The dissociation of 0.15 M phosphoric acid is given by: H3PO4(aq) + H2O(l) ⇄ H2PO4^-(aq) + H3O^+(aq) Ka = 7.1 x 10-3 (at 25°C)   H2PO4^-(aq) + H2O(l) ⇄ HPO4^2-(aq) + H3O^+(aq) Ka = 6.3 x 10-8 (at 25°C)   HPO4^2-(aq) + H2O(l) ⇄ PO4^3-(aq) + H3O^+(aq) Ka = 6.3 x 10-8 (at 25°C)   B. Applying the systematic method in solving acid-base equilibria problems, calculate the pH of the following: a. 0.050 M H3PO4 b. 0.050 M NaH2PO4 c. 0.050 M Na2HPO4

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Chapter9: Acids, Bases, And Salts
Section: Chapter Questions
Problem 9.84E
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The dissociation of 0.15 M phosphoric acid is given by:

H3PO4(aq) + H2O(l) ⇄ H2PO4^-(aq) + H3O^+(aq)

Ka = 7.1 x 10-3 (at 25°C)

 

H2PO4^-(aq) + H2O(l) ⇄ HPO4^2-(aq) + H3O^+(aq)

Ka = 6.3 x 10-8 (at 25°C)

 

HPO4^2-(aq) + H2O(l) ⇄ PO4^3-(aq) + H3O^+(aq)

Ka = 6.3 x 10-8 (at 25°C)

 

B. Applying the systematic method in solving acid-base equilibria problems, calculate the pH of the following:

a. 0.050 M H3PO4

b. 0.050 M NaH2PO4

c. 0.050 M Na2HPO4

d. 0.050 M Na3PO4

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