Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter12: Kinetics
Section: Chapter Questions
Problem 4E: A study of the rate of dimerization of C4H6 gave the data shown in the table: 2C4H6C8H12 (a)...
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Question
Consider the following reaction: CH3X + Y -> CH3Y + X and the experimental data below:
- The graph of 1/[CH3X] versus time was found to be linear.
- The magnitude of the rate constant at 85°C was measured to be 7.88 x 108 (time units = hours)
- The following initial rates data were collected at 25°C:
Experiment | [CH3X]o (M) | [Y]o (M) | Rate (M/hour) |
1 | 4.50 x 10-3 | 3.00 | 5.06 x 10-3 |
2 | 4.50 x 10-3 | 4.50 |
7.58 x 10-3 |
(a) Determine the rate law including the value of k with the appropriate units.
(b) Determine the activation energy for this reaction.
(c) If this reaction is exothermic, sketch a representative diagram of energy versus reaction progress.
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