activation energy

Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter12: Kinetics
Section: Chapter Questions
Problem 4E: A study of the rate of dimerization of C4H6 gave the data shown in the table: 2C4H6C8H12 (a)...
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Consider the following reaction: CH3X + Y -> CH3Y + X and the experimental data below:

  • The graph of 1/[CH3X] versus time was found to be linear.
  • The magnitude of the rate constant at 85°C was measured to be 7.88 x 10(time units = hours)
  • The following initial rates data were collected at 25°C:
Experiment [CH3X]o (M) [Y]o (M) Rate (M/hour)
1 4.50 x 10-3 3.00 5.06 x 10-3
2 4.50 x 10-3 4.50

7.58 x 10-3

(a) Determine the rate law including the value of k with the appropriate units.

(b) Determine the activation energy for this reaction.

(c) If this reaction is exothermic, sketch a representative diagram of energy versus reaction progress.

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