Addition proceeds preferentially through the most stable carbocation intermediate. At high temperature, 10-20 °C or higher, products equilibrate; and the most stable product predominates (thermodynamic control). At low temperature, 0 °C or lower, there is kinetic control of reaction products. Write a mechanism for the first step of this reaction using curved arrows to show electron reorganization. Consult the arrow-pushing instructions for the convention on regiospecific electrophilic attack on a double bond. Arrow-pushing Instructions XE H-CI:

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
Section: Chapter Questions
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Addition proceeds preferentially through the most stable carbocation intermediate. At high temperature, 10-20 °C or higher, products equilibrate; and the most
stable product predominates (thermodynamic control). At low temperature, 0 °C or lower, there is kinetic control of reaction products.
CI
CI
b Write a mechanism for the first step of this reaction using curved arrows to show electron reorganization.
Consult the arrow-pushing instructions for the convention on regiospecific electrophilic attack on a double bond.
Arrow-pushing Instructions
n
→XT
H-CI:
Transcribed Image Text:Addition proceeds preferentially through the most stable carbocation intermediate. At high temperature, 10-20 °C or higher, products equilibrate; and the most stable product predominates (thermodynamic control). At low temperature, 0 °C or lower, there is kinetic control of reaction products. CI CI b Write a mechanism for the first step of this reaction using curved arrows to show electron reorganization. Consult the arrow-pushing instructions for the convention on regiospecific electrophilic attack on a double bond. Arrow-pushing Instructions n →XT H-CI:
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