Ammonia and oxygen react to form nitrogen and water, like this: 4NH; (g)+30,(g) 2N,(g)+6H20(g) Suppose a mixture of NH3, 0,, N, and H,O has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium O to the right The pressure of o, will to the left Some NH, is removed. dn oB go down. not change. The pressure of N2 will (none) O to the right The pressure of NH3 will ? Some N, is added. O to the left The pressure of O2 will ? O (none)

Chemistry: The Molecular Science
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Chapter16: Thermodynamics: Directionality Of Chemical Reactions
Section: Chapter Questions
Problem 105QRT
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Ammonia and oxygen react to form nitrogen and water, like this:
4NH, (g)+ 30,(g) → 2N,(g)+6H,0(g)
Suppose a mixture of NH3, O2, N, and H,0 has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table
below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left.
perturbation
change in composition
shift in equilibrium
to the right
The pressure of 0z will
v ?
Some NH; is removed.
to the left
"dn oB
go down.
not change.
The pressure of N2 will
(none)
to the right
The pressure of NH, will
?
Some N, is added.
O to the left
The pressure of O, will
?
(none)
Transcribed Image Text:Ammonia and oxygen react to form nitrogen and water, like this: 4NH, (g)+ 30,(g) → 2N,(g)+6H,0(g) Suppose a mixture of NH3, O2, N, and H,0 has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium to the right The pressure of 0z will v ? Some NH; is removed. to the left "dn oB go down. not change. The pressure of N2 will (none) to the right The pressure of NH, will ? Some N, is added. O to the left The pressure of O, will ? (none)
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