An EDTA solution is standardized against high-purity CaCO3 by dissolving 0.3982 g CaCO3 in hydrochloric acid, adjusting the pH to 10 with ammoniacal buffer, and titrating. If 38.26 mL was required for the titration, calculate the molarity of the EDTA. (Molecular weight EDTA = 292.24 g mol-1)
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A: volume of EDTA = 20ml volume of CaSO4 = 25ml pH = 10
Q: 3. An EDTA solution is standardized against high purity CaCO3 by dissolving 0.3982 g CaCO3 in…
A: Given data,Mass of CaCO3=0.3982gVolume of EDTA=38.26mLpH=10.0
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A: Solution -
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A: Given mass of MgCO3 = 0.07682 g Volume of water = 1 L Molar mass of MgCO3 = 84.31 g/mol
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Q: which of the following is the concentration of the EDTA solution in terms of molarity?
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A: Millimoles = molarity*volume (in ml) Milligrams= millimoles* molar mass
Q: which of the following is the amount of magnesium in the sample in ppm? (Mg:24 g/mol)
A: Solution: Here Mg2+ ion is Complexometrically titrated with EDTA solution. So the reaction is: Mg2+…
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A: 2)given, initially the volume of Ca2+ = 20.00 mL concentration of Ca2+ = 0.0250 mol/L concentration…
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A: Given: 50.00 mL of 0.1000 M Mn2+ is titrated with 25.00 mL of 0.2000 M EDTA Kf = 7.76 × 1013 α =…
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- Calamine, which is used for relief of skin irritations, is a mixture of zinc and iron oxides. A 1.022-g sample of dried calamine was dissolved in acid and diluted to 250.0 mL. A 50.00 mL aliquot was suitably buffered and titrated with 2.40 mL of 0.002727 M ZnY-2 (Zn-EDTA) solution to allow the following reaction: Fe+3 + ZnY-2 → FeY- + Zn+2. Molecular mass: Fe2O3 = 165.74 a. The weight of sample in the aliquot portion is _________g ? b. the percentage composition of Fe2O3 in the sample is ______ % ?Calculate PCa of the solution that results when 50.0 mL of 0.0050 M Ca2+ is titrated with 25.00 mL of 0.0100 M EDTA in a solution buffered to a conastant pH of 10.00.In order to adjust the EDTA solution, 10 mL of 0.01M Ca + 2 sample was taken and 10 mL of pH 10 buffer was added on it and it was completed to 100 mL. Then, two drops of EBT indicator were added and titrated with EDTA. Since the consumption is 13 mL, what is the concentration of EDTA solution in terms of molarity?
- A 49.10 mL aliquot from a 0.500 L solution that contains 0.530 g of MnSO4 (MW=151.00 g/mol) required 41.6 mL of an EDTA solution to reach the end point in a titration. What mass, in milligrams, of CaCO3 ( MW=100.09 g/mol) will react with 1.53 mL of the EDTA solution?A chemist is given a piece of limestone and told that 50.00% of the sample exists as calcium oxide (CaO). To analyze the sample, the chemist wants to dissolve a portion of the sample in 100 mL and then titrate an aliquot (10 mL) using 0.005300 M EDTA. How much sample (in grams) is needed if a titration volume of 25.00 mL EDTA is desired?What is the equivalence volume when 0.0500 M EDTA is titrated with 100.0 mL of 0.0500 M Mn+ buffered to a pH of 9.00?
- The concentration of a solution of EDTA was determined by standardizing against a solution of Ca2+ prepared from the primary standard CaCO3. A 0.4025 g sample of CaCO3 was transferred into a 250 mL Erlenmeyer flask and the pH adjusted by adding 5 mL of a pH 10 NH3-NH4Cl buffer containing a small amount of Mg2+EDTA. After adding calmagite as a visual indicator, the solution was titrated with the EDTA requiring 42.36 mL to reach the end point. Report the molar concentration of the titrant.Chromel is an alloy composed of nickel, iron and chromium. A 0.6553-g sample was dissolved and diluted to 250.0 mL. When a 50.00-mL aliquot of 0.05173 M EDTA was mixed with an equal volume of the diluted sample, all three ions were chelated, and a 5.34-mL back titration with 0.06139 M copper (II) was required.The chromium in a second 50.0-mL aliquot was masked through the addition of hexamethylenetetramine; titration of the Fe and Ni required 36.98 mL of 0.05173M EDTA. Iron and chromium were masked with pyrophosphate in a third 50.00-mL aliquot, and the nickel was titrated with 24.53 mL of the EDTA solution. Calculate the percentage of Cr in the alloy. Express your answer in 2 decimal places.A 30-mL portion of a solution containing Ca2+ and Mg2+ was titrated with 28.19 mL of 0.213 M EDTA at pH 10. Another 30-mL aliquot of the same Ca-Mg mixture was treated with NaOH to make the solution strongly alkaline and precipitate Mg(OH)2. This solution was then titrated with the same EDTA solution. What would be the required EDTA volume (in mL) to reach the endpoint of the second aliquot if it was found that there was 0.061 M of Mg2+ in the sample?
- A sample of pure CaCO3 weighing 0.3677g is dissolved in hydrochloric acid and the solution diluted to 250.0ml in a volumetric flask. A 25.00ml aliquot requires 30.26ml of an EDTA solution for titration. Calculate a) the molarity of the EDTA solution; b) the number of grams Na2H2Y•2H2O (FW = 372.2) required to prepare 500.0ml of the solution.For complexometric titration of Ca (II) ions in the shell of an egg sample weighing 59,427 g, the necessary processes were applied to the egg shells and a sample of 100 mL was prepared. From the prepared sample, 1 mL was taken and diluted to 100 mL, the pH was adjusted, and two drops of EBT indicator were dripped on it. The prepared solution was titrated with 27.4 mL of EDTA solution set at 0.0097 M. Calculate the amount of calcium in the sample in CaCO3%. (Ca = 40g / mol, CaCO3= 100g / mol)3. An antacid tablet, weighing 1.25 g, was dissolved in a 1.0 L volumetric flask to allow for determination of calcium carbonate and magnesium carbonate contents. After preparing the solution, an aliquot of 10.0 ml was transferred to an Erlenmeyer flask containing a buffer solution with pH = 10. This aliquot was then titrated with EDTA 0.0040 mol/L and the average volume spent was 15.01 mL. To measure calcium after precipitation. After the magnesium was fractionated, a second 10.00 mL aliquot of the stock solution was transferred to an Erlenmeyer flask, and the pH of the present solution was adjusted to a value of approximately 13. In EDTA titration, the volume consumed for observation ofthe end point was equal to 13.03 mL. Based on this information,a) Outline the two steps involved, representing the related reactions./5b) Calculate the concentrations of CaCO3 and MgCO3 present in the initialsolution./6c) Calculate the masses of CaCO3 and MgCO3 present in the pellet./6d) Calculate the…