Answered: As a specific case of the above…

As a specific case of the above question, predict and account for the differences in electronic properties between (a) TiO2 and TiS2, and (b) TiO2 and VO2.

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter14: Applications Of Ultraviolet-visible Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 14.7QAP: A 3.03-g petroleum specimen was decomposed by wet ashing and subsequently diluted to 500 mL in a...

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Concept explainers

Organometallic Compounds of s- and p- block elements

Organometallic compounds have a minimum of one bond between a metal compound and a carbon atom. Metalloid elements such as silicon, tin, and boron form organometallic compounds which can be utilized in a few commercial chemical reactions.

Question

Using periodic trends, crystal structures, valence states, etc., explain the complex spectrum of electronic properties of transition metal compounds (e.g. from TiO to NiO), and describe the main factors that affect the electronic properties, or favour electronic conduction, of inorganic materials. As a specific case of the above question, predict and account for the differences in electronic properties between (a) TiO2 and TiS2, and (b) TiO2 and VO2.

Definition Definition Elements containing partially filled d-subshell in their ground state configuration. Elements in the d-block of the periodic table receive the last or valence electron in the d-orbital. The groups from IIIB to VIIIB and IB to IIB comprise the d-block elements.

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