The anticancer drug cisplatin, cis-[Pt(NH3)2Cl2] (see Figs. 8.12b and 8.33),can be prepared from K2PtCl6 via reduction with N2H4 (hydrazine), givingK2PtCl4, followed by replacement of two chloride ion ligands with ammonia. Give systematic names to the three platinum complexes referred to inthis statement.

Q: Draw the SALC set for the ferrocene ligand set, describing in detail the steps used. Which isomer…

A: In case of ferrocene, the two possible conformations are eclipsed and staggered with a point group…

Q: Which of the following lignads is ( are ) considered as chelate ligand

A: Chelating ligands are those which have more than one donating site and forms a stable ring with…

Q: Ligand A, B, and C form complexes with a metal cation resulting to  violet, indigo, and blue aqueous…

A:

Q: Draw the structures and give the stock names of complexes that can satisfy the following condition:…

A: Chiral compound is a molecule that has asymmetric center that is no plane or center of symmetry.…

Q: Explain the following observations : Zn2+ salts are colourless.

A: The reason for Zn2+ salts are colourless has to be given.

Q: What is the nature of the orbitals involved in the Alq3, from both the metal center and the ligands…

A: The given structure is,

Q: Give the total number of isomers with the formula [RUCI, Br, (NO,),]³-. Treat all nitro ligands as…

A:

Q: Compounds with lone pair of electrons are able to form complexes via the donation of electrons into…

A:

Q: Show how the coordination of two MeHNCH2CH2NH2 ligands to a metal atom in a square planar complex…

A: Optical isomers: Two compound having same molecular formula but different in spatial arrangement…

Q: flouroquinolones like levofloxacin (of the underlying structure) are antibiotics with broad…

A:

Q: ) Define the term “ligand.”  b) Give one similarity and one difference between “monodentate” and…

A: Coordination compounds are the complex that result from coordinate bond between the metal and the…

Q: Cobalt(III) complexes are relatively inert and react very slowly whereas the corresponding…

A: According to kinetics of coordination Compounds we can have two types of compounds Labile compound-…

Q: Compounds with lone pair of electrons are able to form complexes via the donation of electrons…

A: To donate electrons pair, the molecule should have a negative charge or a lone pair of electrons.…

Q: When we consider the reaction of Fe3+ ion (SCN) with its ligand, by showing the ion-ligand bond in…

A: The reaction between Fe3+ and SCN- could be given as, Fe3+aq+SCN-aq→FeSCN2+ SCN- is a thiocyanate…

Q: 2) draw the MO diagrams to show the effect of pi-back bonding in the square planar metal complexes…

A: THE SOLUTION IS SHOWN BELOW.

Q: (a) Which metal in the first transition series (3d series) exhibits +1 oxidation state most…

A: Introduction Transition elements The elements which come between group-2 and group-3. They are…

Q: Nitrogen shows distinct differences from phosphorus and the rest of Group 15. For compounds of N are…

A: Given: Nitrogen and phosphorus both exist in Group 15. We have to find the reason why the compounds…

Q: Define the ambidentate ligand and give two examples.

A: Those ligand which can donate electrons from two different atom site but donate from 1 site at one…

Q: 1. Account for the fact that [SiF6]-2 is a well-known species, while the corresponding [CF6]-2 does…

A: Since, you have asked multiple question, we will solve the first question for you. If you want any…

Q: Draw the structures and give the stock names of complexes that can satisfy the following conditions:…

A:

Q: The periodic trend which is responsible for the observation that the maximum oxidation state of the…

A: The periodic trend which is responsible for the observation that the maximum oxidation state of the…

Q: Regarding the formation of the tetracyanetoniquelate (II) complex answer: a.Demonstrates…

A: As you have posted more than one question , we are doing first for you. To do the rest repost the…

Q: Draw the appropriate completely Orgel Diagram and use it to assign elctronic transition/s to any of…

A:

Q: One of the more striking hydride complexes is [ReH9]2-, which has tricapped trigonal prismatic…

A: Solution -

Q: palladium complexes containing the thiocyanate anion as a ligand were studied. Initially, the square…

A: Coordination compounds exhibits isomerism depending on the geometry of the central metal and the…

Q: Provide two points which support similarities in the organometallic chemistry of the two metals.…

A: Organometallic compound chemistry has a wide variety of use in today's chemistry. Thet are highly…

Q: Consider the [Ir2(dimen)4] 2+ complex. Notice that the dimen ligand is asymmetric. There is also a…

A: The two binuclear complex of Ir metal having the molecular formula [Ir2(dimen)4]2+ and [Ir2(TM4)4]2+…

Q: Explain why, for the same metallic cation and the same ligands, the energy of the binding field is…

A: The question is based on the concept of coordination chemistry. We have to explain the low binding…

Q: Discuss and explain the factors that contribute to the preference of a first row transition metal…

A: This is called the "high-spin" case, because electrons can easily go into the higher orbital. If the…

Q: "Ligand field theory provides a basis for explaining the chemical behaviour of octahedral transition…

A: Ligand field theory was put forward by Hund and Mulliken. According to this theory, all the atomic…

Q: What is a distinguishing feature of the reaction coordinate for ligand substitution at square planar…

A: Certain ligands that are trans to the leaving group have an impact which affect the lability of the…

Q: Explain the following terms giving a suitable example in each case :(i) Ambident ligand(ii)…

A: Following terms are explained below-

Q: 1) draw Electronic absorption spectra of one of the complexes (Y2O3) formed, calculate Ao and Racah…

A: In Y2O3, Yttrium has an oxidation state of +3 and is d0 complex. Hence,  No d-d transition occurs.…

Q: Sketch the orientation of the orbitals relative to the ligandsin an octahedral complex to explain…

A: Crystal field splitting (CFT)-bonding interaction between the transition metals  The orientation of…

Q: a) ) Define transition metal. b) Give the complete electronic configuration for Mn?* and V*".…

A: Given,  a). Define transition metals = ? b). Give the complete electronic configurations of Mn2+ and…

Q: 9. Describe the various ligand classes and give an example in each case! 10. Justify why…

A: Ligand is atom or ion which donate electron density to metal ion.

Q: The coordination complex (complex 1) shown below displays isomerism. Coordination compounds…

A: Since we only answer up to 3 sub-parts, we’ll answer the first 3. Please resubmit the question and…

Q: flouroquinolones like ciprofloxacin are antibiotics with broad antibacterial spectrum widely used…

A: Hello. Since the question contains multiple sub-parts, the first three sub-parts shall only be…

Q: Discuss the structure of chlorophyll from the aspects of coordination chemistry, e.g. oxidation…

A: Chlorophyll is the naturally occurring green pigment in plants that plants use to make their own…

Q: Why does orbital mixing result in pale coloured transition metal complexes? Use diagrams to explain…

A: The d-orbitals of a free metal particle have similar energy when d block elements form coordination…

Q: As a specific case of the above question, predict and account for the differences in electronic…

A: Electronic Properties from TiO to NiO From left to right of 3d transition metal series, (Ti to Ni),…

Q: Give the molecular orbital diagram for the diatomic fluorine 2- ion, including labels for all…

A: Hey, since there are multiple questions posted, we will answer first question. If you want any…

Q: Compare the methyl isocyanide (C=NCH3) ligand to C=0 (carbonyl) with regards to its o donor ability…

A: We have to campare the metal ligand bonding of carbonyl and methyl isocynide ligand.  Both carbonyl…

Q: Explain the following observations: (i) The enthalpies of atomisation of transition metals are quite…

A: The given observations have to be explained,

Q: According to the theory of molecular orbitals, how are ligands classified and what effect do they…

A: On the basis of molecular orbital Theory , ligands are classified into :  1.) Only sigma donor 2.)…

Q: Using the electronic configuration of the transition metals, briefly explain why salts of Cu(II) are…

A: when any iron have an electron then it will colourful because when electromagnetic wave radiation…

Q: A complex of the type [M(AA)2X2]n+ is optically active,giving a suitable example. comment on the…

A: If the substances  which is under observation are non-superimposable mirror images of each other and…

Q: The (2-aminoethyl)phosphine ligand, acts as a bidentate ligand with metals of Transition. i) How…

A: The structure of (2-aminoethyl)phosphine ligand is

Q: (a) Explain the major difference between the number of oxi-dation states of most transition elements…

A: a.

d-Block Elements

According to the modern form of periodic table, 118 elements are present which are subdivided as four blocks, namely, s, p, d and f-block elements based on the entry of the valence electron or last electron into which orbital.