(b) At 80 °C, ethylene dibromide and propylene dibromide mixture forms an ideal solution. Given that the pure vapour pressures of ethylene dibromide and propylene dibromide are 22.9 and 16.9 kPa, respectively. Using the plots of partial vapour pressures of ethylene dibromide and propylene dibromide, and total vapour pressure of the mixture against the mole fraction of ethylene dibromide, determine (i) the composition of the vapour in equilibrium with a solution containing 0.75 mole fraction of ethylene dibromide. (ii) the composition of the liquid phase in equilibrium with ethylene dibromide- propylene dibromide containing 0.5 mole fraction each.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter12: Solutions
Section: Chapter Questions
Problem 12.84QE
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(b) At 80 °C, ethylene dibromide and propylene dibromide mixture forms an ideal solution.
Given that the pure vapour pressures of ethylene dibromide and propylene dibromide
are 22.9 and 16.9 kPa, respectively. Using the plots of partial vapour pressures of
ethylene dibromide and propylene dibromide, and total vapour pressure of the mixture
against the mole fraction of ethylene dibromide, determine
(i) the composition of the vapour in equilibrium with a solution containing 0.75 mole
fraction of ethylene dibromide.
(ii) the composition of the liquid phase in equilibrium with ethylene dibromide-
propylene dibromide containing 0.5 mole fraction each.
Transcribed Image Text:(b) At 80 °C, ethylene dibromide and propylene dibromide mixture forms an ideal solution. Given that the pure vapour pressures of ethylene dibromide and propylene dibromide are 22.9 and 16.9 kPa, respectively. Using the plots of partial vapour pressures of ethylene dibromide and propylene dibromide, and total vapour pressure of the mixture against the mole fraction of ethylene dibromide, determine (i) the composition of the vapour in equilibrium with a solution containing 0.75 mole fraction of ethylene dibromide. (ii) the composition of the liquid phase in equilibrium with ethylene dibromide- propylene dibromide containing 0.5 mole fraction each.
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