Q: Examine whether the complex given below obeys the 18 Electron Rule. Answer using the “B” (neutral…
A: Isusususi
Q: Identify the most likely second-row transition metal for each of the following: a. [M(CO);(NO)I b.…
A:
Q: Copy the structure of EDTA4- from your textbook and circle all six atoms that act as Lewis bases.…
A: EDTA: It's full name is Ethylenediaminetetraacetic acid. It is a chemical that binds certain metal…
Q: lculate IP of Fe when tetradentate ligand above share 4 Ione pairs with Fe?
A:
Q: Mo(PMes)3(C6HS)2
A: The given complex is of the molybdenum which is a a d-group metal (transition metal) and formed…
Q: Water is an example of a ________ ligand. a. unidentate b. None of the given choices c. bidentate d.…
A: Water is an example of MONODENTATE ligand.
Q: Matching Type C. v a monodentate ligand A. EBT D. v a bidentate ligand B. silver diammine E. v a…
A: We have to match the following
Q: 4- using CFT when ligands approach to metal in Octahedral Field, d-Orbitals splitting to a- eg with…
A:
Q: The names of most neutral ligands are unchanged, but an important exception is water, which is…
A: While naming coordination compounds, the name of the neutral ligands remains the same. For example:…
Q: Me3P-M ligand is a pi acceptor or pi donor?
A: A ligand can act as a pi donor or pi acceptor based on the fact that a pi donor ligand will have…
Q: Determine the formula for a complex ion with metal ion X+2 and ligand Y-1 from the following Job's…
A: Introduction: Job's plot is used to find the stereochemistry of the binding event. It is widely used…
Q: The ligand below is abbreviated as det: H2N NH2 a) Identify, then briefly describe, the best way to…
A: Spectrochemical Series is the arrangement of ligands according to their ability to cause crystal…
Q: F3C-M ligand is a pi acceptor/ pi donor or neither?
A: pi acceptor ligands are those in which it have empty p orbitals and a good sigma donor. When bonding…
Q: A good example of multidentate ligand is a. water. b. ammonia. c. EDTA. d. None of the given…
A: Interpretation: A good example of multidentate ligand is to be determined.
Q: Select one a B b . A O From the stability constant ( hypothetical values ) given below , predict…
A: The equilibrium constant for the formation of complex in solution is known as stability constant.
Q: Fe3+ (a hard metal) forms the n stable complex with which of tl Following bases: 1.
A: Hard metal forms stable complex with hard base.
Q: 1-According to Werner formulation, open the structure of the following complexes and predict the…
A:
Q: (c) Please illustrate the orbital overlap that describes "back-bonding" transition metal M–CO…
A: Metal carbonyls are complexes, that involves CO as the ligand. They have both σ and π character.
Q: OUEST. 2. There has been three bands (264 nm, 408 nm and 575 nm) observed in the UV-Vis spectrum of…
A: Crystal field stabilization energy(CFSE ): Depending on the particular ligand field geometry and…
Q: prdination mpound Coordination Magnatic Counter HOMO sphere H.S or LS or N/A proerties ion…
A: The coordination sphere is the cation or anion which consists of a ‘system’ of a central atom…
Q: Consider the following Cu(II) complexes and place them in order of increasing stability. Fully…
A:
Q: Diethylenetriammine, as given below isa _ligand. HNCH,CH,–Ñ– CH,CH,NH, Select one: a. Tetradentate…
A: Ligand: A species that donate its lone pair of electrons to metal ion to form coordinate bond.…
Q: (c) The ligands to meta! charge transfer bands (LMCT) increases in the series Col <CoBr <COCI…
A:
Q: Questions 46 - 50 concem the following ligands A) ethanedioate B) Ammonia C) ethane-1, 2- diamine D)…
A:
Q: [COCI (NH3) 5] C12 Examine whether the complex obeys the effective atomic number rule.
A: The EAN rule means effective atomic number rule. When an atom obeys the EAN rule then it must attain…
Q: Identify the following ligand either is -donor or π-donor or π-acceptor. Explain the reason. PF3…
A:
Q: Which of the following ions/ligands is highest in the spectrochemical series: CO, SO4-2, Br-, ox2-,…
A: Which one of the following is correct answer
Q: 1. Draw the molecular structure of the iron-phenanthroline complex using appropriate software (i.e.…
A: For the spectroscopic determination of iron content in water samples, iron (II) is complexed with…
Q: Although both nitrogen and phosphorous take place in Group VA, in complex formation ammonia acts as…
A: Introduction: Molecular orbital diagram: Molecular orbital diagram shows the chemical bonding in a…
Q: 8 - The crystal field stabilization energy (CFSE) for the [CoClgl* complex is 18000cm1. The A for…
A:
Q: nswer the following questions for a coordinate complex with the name…
A: The word ligand is from Latin which means tie or bind and these ligands may be anions, cations, and…
Q: drawing a suitable structure of the complex below "18 Electron Rule" to show that the suit? Solve…
A: The given complex is, [Pt(η5-C5H5)(NO)] 18 electron rule has to be applied for the given complex. If…
Q: 1). What is chelate effect and why does it occur? Give an example for bidentate ligand along with…
A: When a coordination compound contains chelate ligands, then the Stability of coordination compound…
Q: In the case of ligand substitution at square planar platinum(II), which is the stronger trans effect…
A: Trans effect is a kinetic effect, that is in square planar complex how a ligand trans to the leaving…
Q: Find the correct statement: a a. The more donor atoms a ligand has the greater entropic chelation…
A: The chelate effect refers to chelating ligands' increased affinity for a metal ion compared to a…
Q: Foreach of the following pairs of complexes, identify the one that has the larger Crstal Field…
A:
Q: Hand- draw the structure of the complex below. Predict using the "18 Electron Rule" if the following…
A:
Q: 1. Show the calculation of effective atomic number (EAN) for the complex below. Please explain the…
A: The coordination complexes can be defined as the complex compounds which have a coordinate linkage…
Q: Question about phosphine ligands,.PR3. a) Use a labelled diagram to describe the M-P bonding in…
A: Transition metals forms coordination complexes with neutral or negative ligands . The ligands…
Q: The ligand below is abbreviated as det: H. H2N ZHN. a) Identify, then briefly describe, the best way…
A: A spectrochemical series is a series in which the ligands are arranged in the increasing order of…
Q: descrive four factors that influence the sizes of crystal filed splittings in transition metal…
A:
Q: ce the following coordination complexes in order of bility constant, Bn. Justify your answer.…
A: Chelating agents are the chemical compounds that react with metal ions to form stable water…
Q: (a) Draw the electronic configuration of [NiCl6]3. (b) Determine whether its paramagnetic or…
A: Electronic configuration is defined as the distribution of electrons of an atom or a molecule in…
Q: Loving to another question will save this response. 19 complex [Co(NH3)6l absorbs light at a…
A: Given,the complex [Co(NH3)6]2+ absorbs light at a wavelength 465nm. Calculate the ligand field…
Q: Answer the following questions for square planar metal complexes ML4 (point group Dan): 2) draw the…
A: Electronic configuration of pt78 = [Xe]6s24f145d8
Q: OUEST. 2. There has been three bands (264 nm, 408 nm and 575 nm) observed in the UV-Vis spectrum of…
A: The complex can be written asCrH2O63+ The electronic configuration of chromium…
Q: Draw the ligand field interaction diagram between a square planar ML, fragment with a N* (nitride)…
A: The ligand approaching here is N3- on the ML4 complex its interaction can be shown with a molecular…
Q: From the Job's plot shown, what is ratio of the metal-to-ligand (M:LMT) ?
A: We are provided with a Job's plot and we need to determine the ratio of metal-to-ligand.
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 6 images
- Cis-[PtCl2(NH3)2] is a complex commonly known as cisplatin. When the two chloride ligands in this complex are replaced with the bidentate glycolate ligand (OCH2CO22-), it produces nedaplatin. Given this information, answer the following: Full name of nedaplatin The chemical formula of nedaplatin The primary and secondary valence of the central metalCis-[PtCl2(NH3)2] is a complex commonly known as cisplatin. When the two chloride ligands in this complex are replaced with the bidentate glycolate ligand (OCH2CO22-), it produces nedaplatin. Given this information, answer the following: Full name of nedaplatin The chemical formula of nedaplatin The primary and secondary valence of the central metal metalWhat is the concentration of ligand [L] if this [L] can make 75% of protein bound to it ligand? (kd = 40mM)
- Copy the structure of EDTA4- from your textbook and circle all six atoms that act as Lewis bases. Why does EDTA4- cease to function as a chelating ligand if acid is added to the solution? pls help asap!!Protein X binds to Ligand W with a dissociation constant of .15 μmol. what is the concentration of W 75% of the protein is free (ie, unbound)?"The (2-aminoethyl)phosphine ligand, acts as a bidentate ligand with metalsof Transition.i) How many possible isomers of [dichlorobis{(2-aminoethyl)phosphine}nickel(II)] inoctahedral coordination exist? Draw them and identify the pairs of enantiomers.ii) Classify the configuration of the chiral isomers as D or L
- F3C-M ligand is a pi acceptor/ pi donor or neither?Sketch structure of Mo(DMe) Cl2 (NMe,)2 , thhen apply ean to this complex showing ligand analysis and oxidation state analysisFor which of the following ligands do sigma and pi interactions with the transition metal center go in the same direction? Group of answer choices H2O NH3 OH- CN-
- Consider the [Ir2(dimen)4] 2+ complex. Notice that the dimen ligand is asymmetric. There is also a different, symmetric diisocyano ligand referred to as “TM4” (structure shown to the right) that forms the same sort of binuclear complex that dimen does. Answer the following questions with supporting justification: a. How many geometric isomers (ignore any optical ones) of [Ir2(TM4)4] 2+ are there? b. How many geometric isomers (ignore any optical ones) of [Ir2(dimen)4] 2+ are there? c. In the “twisted” deformational isomer, would you expect [Ir2(TM4)4] 2+ or[Ir2(dimen)4] 2+ to be able to rotate polarized light? Justify your answer.What is the expected number of Fe-Febondsper Fe atom in the complex ?Dimethyldithiocarbamate (abbreviated as dmdtc) is an anionic bidentate ligand with a chemical formula (S2CNMe2)- - where Me stands for methyl group (-CH3). In the photo above, this ligand coordinates to a metal through its 2 sulfur atoms (where M represents a metal). When three dmdtc ligands bind to a ferric ion (Fe3+), a stable coordination complex called ferbam is formed. Given this information, answer / identify the following. complex geometry hybridization type of the central atom coordination number