4- using CFT when ligands approach to metal in Octahedral Field, d-Orbitals splitting to a- eg with high energy and t2g with low energy b- t2g with high energy and eg with low energy c- eg and t2g same energy d- no splitting --- ---

Q: Identify the most likely second-row transition metal for each of the following: a. [M(CO);(NO)I b.…

A:

Q: Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the…

A:

Q: Question 1 Determine the hybridization of the metal centre in the complexes below using Ligand…

A: Since you have posted more than one question , we are doing first one for you. To do the rest repost…

Q: Consider the Tanabe - Sugano diagram for [V(H20)6]²+ octahedral complexes shown below 1. What is the…

A: The most stable electronic arrangement is of lowest energy and is ground state electronic…

Q: Subsequently, derive the p-bonding ligand group orbitals and draw a second qualitative molecular…

A: P- Bonding in ligand group orbital- we will discuss p-bonding in ligand by taking some eexamples-…

Q: The formations of [cis-PtCh(NH3)2] and [trans-PtCl½(NH3)2] are different although same ligands are…

A: The formation of above complex cab be explain by trans effect . the trans effect is the effect that…

Q: on 15 Assuming the 18-electron rule applies for [FeNH3(CO),)]Cl2, the number of carbonyl ligand (n)…

A: The transition metals are capable of forming complexes with ligands such that they can accommodate…

Q: Water is an example of a ________ ligand. a. unidentate b. None of the given choices c. bidentate d.…

A: Water is an example of MONODENTATE ligand.

Q: Which ion would you expect to have the largest crystal field splitting, A? O[Rh(H2016]3+…

A: Note: Since you have asked multiple questions, we will solve the first question for you. If you want…

Q: TABLE 10.10 Angular Overlap Parameters: Sigma Interactions Octahedral Positions Tetrahedral…

A: In the given question, the energy of dxy orbital in the presence of upcoming ligands is needed to be…

Q: Determine the d electron configurationof [Co(H2O)6]2+complex.  A) (t2g)3(eg)2 B) (t2g)4(eg)3 C)…

A: Cobalt aqua complex = [Co(H2O)]2+ Here Co is present in +2 oxidation state. Electronic configuration…

Q: Matching Type C. v a monodentate ligand A. EBT D. v a bidentate ligand B. silver diammine E. v a…

A: We have to match the following

Q: Determine the formula for a complex ion with metal ion X+2 and ligand Y-1 from the following Job's…

A: Introduction: Job's plot is used to find the stereochemistry of the binding event. It is widely used…

Q: 7. Consider the following complexes and enter the requested numbers in (a) and (b): PMes PMes Bu Bu…

A: There are some coordination complexes molecules. We have to calculate the total eletrons count…

Q: 16 - When the ligands move along the x, y and z axes of d orbital in metal ion (octahedral…

A: A coordination complex is formed more electron rich species i.e. ligands approach the metal ion and…

Q: Which orbital is LUMO in the molecular orbital diagram drawn for the sigma interaction of the…

A: We can draw the molecular orbital diagram for the complex to answer the question. LUMO is the lowest…

Q: In which of the following cases all complexes are square planes? (27Co, 28Ni, 46Pd, 78Pt, 79Au)…

A: Coordination complexes  with coordination number 4 can be either tetrahedral or square planar.…

Q: CI Ph2(Et)P-Pt-P(Et)Ph2 EtP-Pt-PEt3 MegP-Pt-CI ČI 242 pm ČI 229 pm CI 237 pm Q.3 For the first…

A: Electronic effect: It influence the structure of molecule, reactivity of molecule, or properties of…

Q: 1-According to Werner formulation, open the structure of the following complexes and predict the…

A:

Q: Determine the hybridization of the metal centre in the complexes below using Ligand Field Theory.…

A:

Q: 1 R3P" d. Consider complex 1. i. Draw a molecular orbital (MO) energy level diagram to describe the…

A:

Q: Calculate the Ligand-field stabilization energies (LFSE) for octahedral compounds which contain the…

A: The high spin complexes contain the unpaired electrons whereas the low spin complexes contain the…

Q: (c) The ligands to meta! charge transfer bands (LMCT) increases in the series Col <CoBr <COCI…

A:

Q: :Which metal carbonyl in each of -2- or [Co(CO)4][Fe(CO)4] (a) -or [Re(CO)5] -[Mn(CO)5] (b) *…

A: The ligand carbonyl is a strong σ donor but it also accepts the ∏ electrons from metals. This makes…

Q: Give a scientific reason for each of the following: 1- No known tetrahedral ionic complexes.(Pd + 2,…

A: Few questions about coordination chemistry, which are to be accomplished.

Q: Which of the following ions/ligands is highest in the spectrochemical series: CO, SO4-2, Br-, ox2-,…

A: Which one of the following is correct answer

Q: Determine the d electron configurationof [OsCl6]3-complex. A) (t2g)4(eg)2 B) (t2g)5(eg)0 C)…

A: Complex = [OsCl6]3- Here Os is present in +3 oxidation state.  Electronic configuration of Os(Z=76)…

Q: Q5 Below are the Period 4 transition metals. Indicate on the table: a) the element that forms an…

A: 18 electron rule  The 18 electron rule is used primarily for prediction and rationalizing formula…

Q: When the valence d orbitals of the central metal ion are split in energy in an octahedral ligand…

A: Question.1:-  When the valance d-orbital of central atom split in energy in an octahedral ligand…

Q: Biding curve for a ligand X to a macromolecule A, B, and C are shown below. A B 1.5- 0.5-

A: The initial slope of the binding curve, at low ligand concentration ([L]= 0.1 ×Kd), is given by…

Q: Does p-d mixing in electronic spectrum  of [Mn(Br)4]2- occur due the pi-donating bromine ligand .…

A: Answer : Part 1:  Yes, p-d mixing in electronic spectrum of [Mn(Br)4]2- occur due to the pi-donating…

Q: For which member of the following pairs of complexes would A. be larger and why? i [Cr(H:O)k]* and…

A: By comparing ligand field strength and central metal ion we can decide the value of Δo for a…

Q: 5) Rank the following sigma complexes in order of increasing stability. H **$$ Br Br H NO₂ + A H Br…

A: Given:

Q: Magnetic moment of a first-row transition-metal complex M (H,O), is 3.9 Bohr magnetons. Identify the…

A:

Q: H. F3C-M

A: Pi donor means ligand which donate pi electron density to metal . Pi acceptor means metal transfer…

Q: A first-row transition-metal complex of formula [M(H2O)6]²+ has a magnetic moment of 3.9 Bohr mag-…

A: Given: Magnetic moment = 3.9 B.M Complex is MH2O62+, here M is first-row transition metal

Q: Predict the d orbital splitting of [RuCl6]2-complex. A) (t2g)2(eg)3 B) (t2g)4(eg)2 C) (t2g)3(eg)1…

A: Complex = [RuCl6]2- In this complex, Ru present in +4 oxidation state.  Electronic configuration of…

Q: Which of the following complexes are chiral? 1: [Ru(ena2 II: [Pt(dien)C* II: cis-Cr(C2O4hCh]3- IV:…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: Hand- draw the structure of the complex below. Predict using the "18 Electron Rule" if the following…

A:

Q: 1- The gap between the higher and lower energy levels is called (CFSE). 2- Splitting of d orbitals…

A: As per the rules, only the first three sub-parts of a question can be answered: Co-ordination…

Q: 1-Explain the bonding nature of [Fe(CN)5 (NO)]-2 linear NO ligand. Vour anewer

A: Applying concept of 18e- rule.

Q: Determine the d orbital splitting of [FeCl4]-complex. A) (e)0(t2)5 B) (t2)3(e)2 C) (t2)5(e)0 D)…

A:

Q: Answer the following questions for a square planar complex that has a dº metal center. a) What is…

A: The crystal field stabilization energy can be calculated as: CFSE=4(-0.51∆∘)+2(-0.43∆∘)+2(+0.23∆∘)+P…

Q: 1) Determine the d electron configurationof [Ni(CO)4] complex.  A) (e)4(t2)6 B) (e)4(t2)2 C)…

A: CO is a neutral ligand. In [Ni(CO)4], Ni is present as zero oxidation number.  Ni^0 : 3d^84s^2 ~…

Q: i, d electron configuration ii crystal field theory summary i high/low-spin assignment based on…

A: (i)d electron configuration  Electronic configuration = (n-1)d1-10ns1-2 the element of d block have…

Q: (g (n' (h M(n-CSH5):(CO)(M=M bond) 3 Calculate the Total Valence Electron (TVE) and sketch the…

A: Total valence electrons of a complex is equals to the valence electron of metal (d + s electrons)…

Q: Which of the following ligands will increase the value of A,? CN', CO, CI", N3-, en O Ct, N3- CO…

A: The Crystal Field Splitting (Δo) depends upon the nature of the ligands. The ligands which cause…

Q: raw the hybridization for the metal centre of the complex below. You need to determine the geometry…

A: Since you have posted more than 1 question, we are doing 1st one for you. To do the rest repost the…

Q: H H - N - H H C- H H - N - C-H | H-C- F: (CH3)2NH CH3NH2 NH3 NF3

A: Welcome to bartleby ! We have to tell the steric number and coordination geometry of central atom