Although both nitrogen and phosphorous take place in Group VA, in complex formation ammonia acts as sigma-donor while PR3 is both sigma–donor and pi-acceptor. In the light of this explanation, show the sigma and pi interactions in [Co(PR3)6]2+ according to MO theory. What makes PR3 a different ligand than ammonia? Do I need to replace t2g orbitals in my diagram? How can I show PR3 ligands using d orbitals?

Although both nitrogen and phosphorous take place in Group VA, in complex formation ammonia acts as sigma-donor while PR3 is both sigma–donor and pi-acceptor. In the light of this explanation, show the sigma and pi interactions in [Co(PR3)6]2+ according to MO theory. What makes PR3 a different ligand than ammonia? Do I need to replace t2g orbitals in my diagram? How can I show PR3 ligands using d orbitals?

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter7: Statistical Data Treatment And Evaluation

Section: Chapter Questions

Problem 7.9QAP

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