C1....... Cu ***.... CI 5. Answer the following questions related to crystal field splitting. A. For an Octahedral complex, draw the crystal field splitting for both a high spin, and low spin d5 complex. Correctly label symmetry labels for orbitals, and identify the amount of unpaired electrons for each splitting diagram. Consider the square base pyramidal [CuCls]3 complex. Using the provided reference system and with the knowledge that its point group is Cav, answer the following questions: CI CI y B. What is the oxidation state of each atom apart of the system. Cu: Cl: C. Draw the Crystal field splitting for the complex listed above. Assume that each ligand is a point charge which the extent of the overlap with the d-orbitals from Cu will determine the energy level of each. Label the energy scale, correctly position the d-orbitals in their respective energy levels, label each d-orbital with the correct symmetry label, and fill in correct number of electrons.

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Chapter21: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 108IP: a. In the absorption spectrum of the complex ion Cr(NCS)63, there is a band corresponding to the...
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5.
Answer the following questions related to crystal field splitting.
A. For an Octahedral complex, draw the crystal field splitting for both a high spin, and low spin d5
complex. Correctly label symmetry labels for orbitals, and identify the amount of unpaired electrons
for each splitting diagram.
Consider the square base pyramidal [CuCls]3 complex. Using the provided reference system and with
the knowledge that its point group is CAv, answer the following questions:
Cu
...... C
В.
What is the oxidation state of each atom apart of the system.
Cu:
Cl:
C. Draw the Crystal field splitting for the complex listed above. Assume that each ligand is a point
charge which the extent of the overlap with the d-orbitals from Cu will determine the energy level of
each. Label the energy scale, correctly position the d-orbitals in their respective energy levels, label
each d-orbital with the correct symmetry label, and fill in correct number of electrons.
Transcribed Image Text:5. Answer the following questions related to crystal field splitting. A. For an Octahedral complex, draw the crystal field splitting for both a high spin, and low spin d5 complex. Correctly label symmetry labels for orbitals, and identify the amount of unpaired electrons for each splitting diagram. Consider the square base pyramidal [CuCls]3 complex. Using the provided reference system and with the knowledge that its point group is CAv, answer the following questions: Cu ...... C В. What is the oxidation state of each atom apart of the system. Cu: Cl: C. Draw the Crystal field splitting for the complex listed above. Assume that each ligand is a point charge which the extent of the overlap with the d-orbitals from Cu will determine the energy level of each. Label the energy scale, correctly position the d-orbitals in their respective energy levels, label each d-orbital with the correct symmetry label, and fill in correct number of electrons.
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