Give a scientific reason for each of the following: 1- No known tetrahedral ionic complexes.(Pd + 2, Pt + 2 ) 2- The strength of the ligands CN, CO ? 3- The cleavage of d orbitals in C.F.T. by the influence of the ligands, where the high level eg and the low level of t2g are observed. 4- Werner's coordination theory succeeded in explaining its complexes. Subject: inorganic chemistry I hope for a quick solution

Q: The ligand-field strength also depends on the identity of the central ion, the order being Mn2+ <…

A:

Q: (a) A compound with formula RuCl3 . 5 H2O is dissolved inwater, forming a solution that is…

A: a.

Q: Question three and four

A: Since you have posted multiple question, we are entitled to answer the first only.

Q: d. Fig. 10.41 The occupation of energy levels in a d'octahedral complex.

A:

Q: Which of the following is responsible for the chelate effect exhibited by multidentate ligands? a.…

A: This question is related to coordination Chemistry. Coordination complexes are the molecules in…

Q: Consider the coordination compouná ammonium hexacyanoferrate(III a What is the charge on the complex…

A: We have to find the charge on the complex ion for the following given compound as follows in step 2:

Q: Bearing in mind the Jahn-Teller theorem, explain what type of distortion can be expected for [VCl,]³…

A:

Q: 20

A: In given complex [Cr(H2O)6]2+ there are 4 unpaired electrons and one eg orbital are present. Ligand…

Q: out the Alfred warner theory of complexation charge (all are correct except Select one: 1-the…

A: Welcome to bartleby !

Q: Consider the square base pyramidal [CuCls]3 complex. Using the provided reference system and with…

A: Let us first discuss the oxidation state and then its geometry. Finally we can draw the d orbital…

Q: CI Ph2(Et)P-Pt-P(Et)Ph2 EtP-Pt-PEt3 MegP-Pt-CI ČI 242 pm ČI 229 pm CI 237 pm Q.3 For the first…

A: Electronic effect: It influence the structure of molecule, reactivity of molecule, or properties of…

Q: 1-According to Werner formulation, open the structure of the following complexes and predict the…

A:

Q: Using only sigma overlap parameters, a 5-coordinate dº complex TABLE 10.10 Angular Overlap…

A: In the given problem the preferential geometry of a 5-coordinated d6 complex is needed to determined…

Q: One of these is incorrect about the limitations of the Valence Bond Approach اختر احدى الدجابات It…

A: Answer:- This question is answered by using the simple concept of valence bond theory for complex or…

Q: 3. The coordination geometries around the nickel atom in the nominally six-coordinate complexes…

A:

Q: OUEST. 2. There has been three bands (264 nm, 408 nm and 575 nm) observed in the UV-Vis spectrum of…

A: Crystal field stabilization energy(CFSE ): Depending on the particular ligand field geometry and…

Q: Please help with this work. Derive the free-ion term (show the steps) and (b) find (ONLY) the ground…

A: This is multi part questions and as per answering guidelines I can only answer first 3 questions if…

Q: 10.19 Explain the order of the magnitudes of the following A, values for Cr(III) complexes in terms…

A: Here CN-is a strong field ligand that is a sigma donor and Pie acceptor type ligand that why its Del…

Q: 3. For the complex [N(Et)-][V(CO)«] (where Et = C2H3) a) Give the name of the complex, and what is…

A: The given complex is  [N(Et)4][V(CO)6], Where Et = Ethyl

Q: The metal ion, M2+, formed a paramagnetic tetrahedral complex [MJ4]2+, having three unpaired…

A: The given metal ion is M2+

Q: How did conductivity help to confirm the structure of complexes [Co(NH3)4CO3]NO3 and [Co(NH3)5Cl]Cl2

A: The conductivity measurement of a coordination compoud [Co(NH3)4CO3]NO3  shows that it dissociates…

Q: Many coordination complexes are present in our body. These complexes take part in different…

A: Following is the structure of cobalamine and the answers of the given questions are as follows.

Q: Determine the d electron configurationof [OsCl6]3-complex. A) (t2g)4(eg)2 B) (t2g)5(eg)0 C)…

A: Complex = [OsCl6]3- Here Os is present in +3 oxidation state.  Electronic configuration of Os(Z=76)…

Q: Questions about organometallic complexes. a) Transition metal species are classified as Werner or…

A: Ligands are attached to the transition elements. They donate electrons to the metal and form a…

Q: The stepwise stability constant in aqueous solution for the formation of copper complexes with NH3…

A:

Q: Do you expect any tetragonal distortion from octahedral structures of the following complexes.…

A: The Jahn Teller Effect is a geometric distortion of a non linear molecular system that reduces its…

Q: Indicate the (i) metal oxidation state, (ii) d- electron count, and (iii) the spin only magnetic…

A:

Q: Sketch structure of Mo(DMe) Cl2 (NMe,)2 , thhen apply ean to this complex showing ligand analysis…

A: The given chemical formula is: Mo(DMe) Cl2 (NMe)2 Assuming that DMe is OMe (methoxy group). The new…

Q: 13. Using d-orbital splitting diagrams, please determine which of following complexes can exhibit…

A: Jahn-Teller effect refers to the distortion which occurs in the non-linear molecule. Due to this…

Q: 3) The yttrium complex depicted below was isolated by the Evans lab at UC Irvine. It must be handled…

A: The organometallic complex of Yttrium contains an N22- molecule.

Q: TiCl(Cp)2(CN)] and [TiCl(Cp)2(NH3)]Cl  [IrMe(PMe3)4] and [Ir(C≡C-Ph)(PMe3)4]   - Include the…

A: There are some coordination complexes .... 1) [TiCl(Cp)2(CN)] and [TiCl(Cp)2(NH3)]Cl  2)…

Q: 9. Describe the various ligand classes and give an example in each case! 10. Justify why…

A: Ligand is atom or ion which donate electron density to metal ion.

Q: 1. Examine the x-ray crystallography structure of a nickel Ni coordination complex. i. Identify the…

A: The transition metal complexes are those in which the central metal atom belongs to the d-block of…

Q: catahedral” Cu (II) complexes are often described as having a (4+2)- coordination pattern. Suggest…

A:

Q: Consider the reactions below. Which of the following correctly identifies the coordinate complex?…

A:

Q: After the NH3 molecules acted as Bronsted bases in the reaction with aqueous HCl they became NH4 +…

A: Concept:  A Ligands can be a ions or neutral molecules that bond to a central metal atom or ion.…

Q: 6. What are the differences between these complexes [Co(NH3)6]Cl3 , [Co(H20)6]Cl2, (Base your answer…

A: CFT is the concept of solid-state physics used to explain the properties of coordination complexes.…

Q: (a) Give names of two complexes which are used in medicines.(b) Using valence bond theory of…

A: Since you have asked multiple questions, we will solve the first question for you. If you want any…

Q: 6) Complexes with five d electrons (d) are sometimes tetrahedral and sometimes octahedral. Consider…

A: Given is  ∆o =11000 cm-1 And we have to determine ∆t Also we know that  ∆t = 4/9 ∆o

Q: What is the charge on each of the following complex ions? hexaaquairon(II), [Fe(H2O)6]?…

A: 1.) Charge on hexaaquairon(II) Is +2   The oxidation state or charge on the central metal ion, Fe =…

Q: 1. The UV-visible spectrum of an aqueous solution of CuSO, (which contains a Cu2+ metal center)…

A: ∆Oct is an energy term, representing the energy gap between the splitted orbitals and have an…

Q: When MCl4(NH3)2 is dissolved in water and treated withAgNO3, 2 mol of AgCl precipitates immediately…

A: When MCl4(NH3)2 is dissolved in water and treated withAgNO3, 2 mol of AgCl precipitates immediately…

Q: 6.) a.) In the series of Werner complexes (after the German-Swiss chemist) [CoX(NH3)s]** with X =l',…

A:

Q: 15. In 1844, cis- and trans-[PtCl2(NH3)2] were discovered. The FDA approved the anti-cancer drug…

A:

Q: ce the following coordination complexes in order of bility constant, Bn. Justify your answer.…

A: Chelating agents  are the chemical compounds  that react with  metal ions  to form stable  water…

Q: 1. Using the MO scheme provided below, calculate the bond order for the ligand-metal bonds in a ML6…

A: Electron configuration of Co: [Ar] 3d7 4s2 Electron configuration of Co2+: [Ar]3d7 There are 6 NH3…

Q: Short questions, all-or-nothing. There may be more than one answer per question. axial 3- CN NC Ni…

A:

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.