(on each page) Last Name (on each page) Chapter 12: Reactions in Coordination Chemistry 20. The high-spin complex [Cr(H2O)o]²* is labile towards ligand substitution, but the low- spin complex [Cr(CN)6]+- is inert. Offer an explanation. 21. Sketch one reaction profile that is consistent with all three of the following statements: (a) The starting four-coordinate ML3X reactant complex is inert toward substitution by the ligand, Y. (b) The conversion of ML3X + Y to ML3Y +X is an exothermic process. (c) A five-coordinate ML3XY species is observed during the course of the reaction. etal present in

Principles of Modern Chemistry
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ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
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Last Name
(on each page)
Chapter 12: Reactions in Coordination Chemistry
20. The high-spin complex [Cr(H2O)o]²* is labile towards ligand substitution, but the low-
spin complex [Cr(CN)6]+- is inert. Offer an explanation.
21. Sketch one reaction profile that is consistent with all three of the following
statements:
(a) The starting four-coordinate ML3X reactant complex is inert toward substitution by
the ligand, Y.
(b) The conversion of ML3X + Y to ML3Y +X is an exothermic process.
(c) A five-coordinate ML3XY species is observed during the course of the reaction.
etal present in
Transcribed Image Text:(on each page) Last Name (on each page) Chapter 12: Reactions in Coordination Chemistry 20. The high-spin complex [Cr(H2O)o]²* is labile towards ligand substitution, but the low- spin complex [Cr(CN)6]+- is inert. Offer an explanation. 21. Sketch one reaction profile that is consistent with all three of the following statements: (a) The starting four-coordinate ML3X reactant complex is inert toward substitution by the ligand, Y. (b) The conversion of ML3X + Y to ML3Y +X is an exothermic process. (c) A five-coordinate ML3XY species is observed during the course of the reaction. etal present in
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