Calculate of the expected pH of the solution in beaker 3 after the addition of 20 mL of 1.0 M HCl. Beaker 3 volume: 100mL Beaker 3 (1.0M CH3CO2H & 1.0M NaCH3CO2) pH init: 4.73 Breaker 3 (1.0M CH3CO2H & 1.0M NaCH3CO2) pH final: 4.56

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter16: Reactions Between Acids And Bases
Section: Chapter Questions
Problem 16.52QE
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Calculate of the expected pH of the solution in beaker 3 after the addition of 20 mL of 1.0 M HCl.

Beaker 3 volume: 100mL

Beaker 3 (1.0M CH3CO2H & 1.0M NaCH3CO2) pH init: 4.73

Breaker 3 (1.0M CH3CO2H & 1.0M NaCH3CO2) pH final: 4.56

 

Expert Solution
Step 1

Step 1:

From the given condition, initial pH of beaker 3 is 4.73.

The volume is 100 ml=0.1L

Solutions in the beaker are: 1.0M CH3COOH  and 1.0M  CH3COONa.

The initial moles are, calculated as follows:

Chemistry homework question answer, step 1, image 1

Thus, the Handerson Hasselbaach equation is applied as follows:

Chemistry homework question answer, step 1, image 2

Now, putting the values it is obtained as:

Chemistry homework question answer, step 1, image 3

Thus, the pKa is obtained is 4.73.

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