Calculate the enthalpies of formation, AH;, of group 1 chloride compounds from their elements by using the Born- Haber cycle. Process ΔΗ', kJ/mol Sublimation of Li(s) 161 Sublimation of Cs(s) 78 Dissociation of Cl, (g) 244 Ionization energy of Li(g) 513 Ionization energy of Cs(g) 376 Electron affinity of Cl(g) -349 Lattice enthalpy of LiCl(s) 852 Lattice enthalpy of CsCl(s) 676 AH; of LiCl = kJ/mol AH; of CsCl = kJ/mol

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter3: Atomic Shells And Classical Models Of Chemical Bonding
Section: Chapter Questions
Problem 10P
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Calculate the enthalpies of formation, AH;, of group 1 chloride compounds from their elements by using the Born-
Haber cycle.
Process
ΔΗ, k/mol
Sublimation of Li(s)
161
Sublimation of Cs(s)
78
Dissociation of Cl, (g)
244
Ionization energy of Li(g)
513
Ionization energy of Cs(g)
376
Electron affinity of Cl(g)
-349
Lattice enthalpy of LiCl(s)
852
Lattice enthalpy of CsCl(s)
676
AH; of LiCl =
kJ/mol
AH; of CsCl =
kJ/mol
Transcribed Image Text:Calculate the enthalpies of formation, AH;, of group 1 chloride compounds from their elements by using the Born- Haber cycle. Process ΔΗ, k/mol Sublimation of Li(s) 161 Sublimation of Cs(s) 78 Dissociation of Cl, (g) 244 Ionization energy of Li(g) 513 Ionization energy of Cs(g) 376 Electron affinity of Cl(g) -349 Lattice enthalpy of LiCl(s) 852 Lattice enthalpy of CsCl(s) 676 AH; of LiCl = kJ/mol AH; of CsCl = kJ/mol
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