Calculate the expected ΔHrxn using the ΔHf values for the reactants and products in the Reaction. (Hint: this is actually much easier if you write the net reaction first and then calculate ΔHrxn for the net.) HCl(aq) + NaOH(aq) -> H2O(l) + NaCl(aq) i attached the table for the problem and my work up to this point. plz only solve for trial one. i am wondering how delta H will change when the concentration of HCl changes. Note the lab question is How does the concentration of acid affect the heat of reaction (ΔHrxn)between a strong acid (HCl) and a strong base(NaOH)?

World of Chemistry, 3rd edition
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Chapter10: Energy
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Problem 8A
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Calculate the expected ΔHrxn using the ΔHf values for the reactants and
products in the Reaction. (Hint: this is actually much easier if you write
the net reaction first and then calculate ΔHrxn for the net.)

HCl(aq) + NaOH(aq) -> H2O(l) + NaCl(aq)

i attached the table for the problem and my work up to this point. plz only solve for trial one. i am wondering how delta H will change when the concentration of HCl changes. Note the lab question is

How does the concentration of acid affect the heat of reaction (ΔHrxn)between a strong acid (HCl) and a strong base(NaOH)?

this is for reference

 

 

Table 1: Trial Data
Mass of cups (g)
Volume of HCI (mL)
Volume of NaOH (mL)
3.509
50
50
NaOH concentration (M)
0.955
Initial temperature of compounds (°C)
17.75
Trial #1
Trial #2
Trial #3
HCl concentration (M)
0.923
0.692
0.462
Final temperature of compounds (°C)
Mass of solution (kg)
24.3
22.8
21.2
0.103255
0.10199
0.102134
AT (°C)
6.55
5.05
3.35
Energy/q (kJ)
Change in enthalphy/AHrxn (kJ/mol)
3.57
2.15
1.43
-55.83
-55.83
-55.83
Transcribed Image Text:Table 1: Trial Data Mass of cups (g) Volume of HCI (mL) Volume of NaOH (mL) 3.509 50 50 NaOH concentration (M) 0.955 Initial temperature of compounds (°C) 17.75 Trial #1 Trial #2 Trial #3 HCl concentration (M) 0.923 0.692 0.462 Final temperature of compounds (°C) Mass of solution (kg) 24.3 22.8 21.2 0.103255 0.10199 0.102134 AT (°C) 6.55 5.05 3.35 Energy/q (kJ) Change in enthalphy/AHrxn (kJ/mol) 3.57 2.15 1.43 -55.83 -55.83 -55.83
a) (msolution) = total mass
(msolution) = 106.764g – 3.509g = 103.255g
b) AT = Tt - Ti
AT = 24.30°C – 17.75°C = 6.550°C
c) q = m*Cs* AT
q = 0.103255kg * 4.184kJ/K*6.550°C = 3.56966kJ
d) n(HCI) = (0.923mol/L)(50mL)(1L/1000mL) = 0.046mol
n(NaOH) = (0.955mol/L)(50mL)(1L/1000OmL) = 0.048mol
According to the balanced equation: HCI(aq)+NaOH(aq)→NaCI(aq)+H
20(1), the stoichiometric ratio between the moles of HCl and the product
moles of H20 produced is of a 1:1 ratio, thus 0.046mol of HCI will react
with 0.048mol of NaOH to produce 0.046mol of H2O
mass of cups
Transcribed Image Text:a) (msolution) = total mass (msolution) = 106.764g – 3.509g = 103.255g b) AT = Tt - Ti AT = 24.30°C – 17.75°C = 6.550°C c) q = m*Cs* AT q = 0.103255kg * 4.184kJ/K*6.550°C = 3.56966kJ d) n(HCI) = (0.923mol/L)(50mL)(1L/1000mL) = 0.046mol n(NaOH) = (0.955mol/L)(50mL)(1L/1000OmL) = 0.048mol According to the balanced equation: HCI(aq)+NaOH(aq)→NaCI(aq)+H 20(1), the stoichiometric ratio between the moles of HCl and the product moles of H20 produced is of a 1:1 ratio, thus 0.046mol of HCI will react with 0.048mol of NaOH to produce 0.046mol of H2O mass of cups
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