Calculate the volume occupied by 1.00 mol N2 using the van der Waals equation expanded into the form of a virial expansion at (a) its critical temperature, (b) its Boyle temperature. Assume that the pressure is 10 atm throughout. At what temperature is the behaviour of the gas closest to that of a perfect gas? Use the following data: Tc = 126.3 K, TB = 327.2 K, a = 1.390 dm6 atm mol−2, b = 0.0391 dm3 mol−1.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter6: The Gaseous State
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Problem 6.126QE
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Calculate the volume occupied by 1.00 mol N2 using the van der Waals equation expanded into the form of a virial expansion at (a) its critical temperature, (b) its Boyle temperature. Assume that the pressure is 10 atm throughout. At what temperature is the behaviour of the gas closest to that of a perfect gas? Use the following data: Tc = 126.3 K, TB = 327.2 K, a = 1.390 dm6 atm mol−2, b = 0.0391 dm3 mol−1.

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