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CH CH3 CH3 (I) „CH3 (II) „CH3 (III) CH, (IV) (V) IOH CH HO Step I

CH CH3 CH3 (I) „CH3 (II) „CH3 (III) CH, (IV) (V) IOH CH HO Step I

Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter14: Elimination
Section: Chapter Questions
Problem 10CTQ
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QUESTION 1 Identify the reagent(s) from Table I required for individual steps of the multistep synthetic sequence below. Then place the number(s) (A1, A2 C1, C2 ...) that represents the reagent(s) in the given box right next to the corresponding step number (I, II, II...). You will be graded based on the number(s) in each box. If two sets of reagents are required sequentially for the same step, place both numbers in the same box in the proper order separated by a comma without any additional space (e.g., A1,A2). Do not fill in any single box with more than two numbers. The same reagents can be used in multiple steps if B1, B2..., or ... Table I Number Reagent Number Reagent Number Reagent A1 K B1 Mg, ether C1 CH2O A2 NaOH B2 NaBHa, CH3ОH C2 CH3CHO АЗ CH;ONa, CH3OH B3 1. LIAIH4; 2. H3O* C3 A4 t-BUOK B4 H2, Raney Ni C4 CH3OH needed. A5 H2SO4 B5 РСС C5 CH;COOCH3 A6 HBr B6 Na2Cr207, H2SO4 C6 CH;CH2I A7 H3O* B7 PBR3 C7 1. CН:ОН, 1. H20, Hg(OAc)2; 2. NaBH4 1. BH3-THF; 2. H2O2, NAOH OsO4, H2O2 A8 B8 C8 Hg(OAc)2; 2. NaBH4 A9 B9 Br2. H20 C9 A10 B10 МСРВА C10 A11 1. O3; 2. (CH3)2S B11 NBS (hv) C1
Transcribed Image Text:QUESTION 1 Identify the reagent(s) from Table I required for individual steps of the multistep synthetic sequence below. Then place the number(s) (A1, A2 C1, C2 ...) that represents the reagent(s) in the given box right next to the corresponding step number (I, II, II...). You will be graded based on the number(s) in each box. If two sets of reagents are required sequentially for the same step, place both numbers in the same box in the proper order separated by a comma without any additional space (e.g., A1,A2). Do not fill in any single box with more than two numbers. The same reagents can be used in multiple steps if B1, B2..., or ... Table I Number Reagent Number Reagent Number Reagent A1 K B1 Mg, ether C1 CH2O A2 NaOH B2 NaBHa, CH3ОH C2 CH3CHO АЗ CH;ONa, CH3OH B3 1. LIAIH4; 2. H3O* C3 A4 t-BUOK B4 H2, Raney Ni C4 CH3OH needed. A5 H2SO4 B5 РСС C5 CH;COOCH3 A6 HBr B6 Na2Cr207, H2SO4 C6 CH;CH2I A7 H3O* B7 PBR3 C7 1. CН:ОН, 1. H20, Hg(OAc)2; 2. NaBH4 1. BH3-THF; 2. H2O2, NAOH OsO4, H2O2 A8 B8 C8 Hg(OAc)2; 2. NaBH4 A9 B9 Br2. H20 C9 A10 B10 МСРВА C10 A11 1. O3; 2. (CH3)2S B11 NBS (hv) C1
CH CH3 „CH3 (II) „CH (IV) (V) CH3 (I) „CH3 (II) CH3 Step I Step II Step III Step IV Step V
Transcribed Image Text:CH CH3 „CH3 (II) „CH (IV) (V) CH3 (I) „CH3 (II) CH3 Step I Step II Step III Step IV Step V
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