chemist is titrating  57.7mL  of a  0.2900M  solution of formic acid  H2CO2  with a

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter15: Acid-base Equilibria
Section: Chapter Questions
Problem 88AE: Consider die titration of 50.0 mL of 0.10 M H3A (Ka1 = 5.0 104, Ka2 = 1.0 108, Ka3 = 1.0 1012)...
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An analytical chemist is titrating 

57.7mL

 of a 

0.2900M

 solution of formic acid 

H2CO2

 with a 

0.9700M

 solution of 

KOH

. The 

pKa

 of formic acid is 

3.74

. Calculate the pH of the acid solution after the chemist has added 

7.03mL

 of the 

KOH

 solution to it.

 

Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of 

KOH

 solution added.

 

Round your answer to 

2

 decimal places.

 

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