12 Note: This is a 2 point question. The reaction below is first order with respect to NO and second order with respect to Cl, Determine the value of the rate constant and write the rate law. 14 15 2 NO + Cl2 (e) (2) → 2 NOCI (e) Initial [NO] Initial [Cl] Initial Rate (M/s) 18 Experiment 0.0255 -- 0.0125 M 2. 0.0125 M 0.0510 21 0.0250 M 0.0255 4.55 x 10-5 3. Rate = 0.00370 M2s- [NOe]? [Clze] to O Rate = 2.79 M25- [NO)] [Clze]! Rate = 0.0712 M's'[NO2] [Cl} O Rate = 5.70 M's' [NO2]' [Cll² Rate = 5.70 M²²s²1 [NO]² [Cly«]' %3D Rate = 2.79 M2s1 [NO]' [C»el° Rate = 0.00370 M2s [NO2(2)] [C2el* Rate = 0.0712 M's[NO2] [Cl2(g)]

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 5PS: Experimental data are listed here for the reaction A 2 B. (a) Prepare a graph from these data;...
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12
Note: This is a 2 point question.
The reaction below is first order with respect to NO and second order with respect to
Cl, Determine the value of the rate constant and write the rate law.
14
15
2 NO
+ Cl2 (e)
(2)
→ 2 NOCI (e)
Initial [NO]
Initial [Cl]
Initial Rate (M/s)
18
Experiment
0.0255
--
0.0125 M
2.
0.0125 M
0.0510
21
0.0250 M
0.0255
4.55 x 10-5
3.
Rate = 0.00370 M2s- [NOe]? [Clze]
to
O Rate = 2.79 M25- [NO)] [Clze]!
Rate = 0.0712 M's'[NO2] [Cl}
O Rate = 5.70 M's' [NO2]' [Cll²
Rate = 5.70 M²²s²1 [NO]² [Cly«]'
%3D
Rate = 2.79 M2s1 [NO]' [C»el°
Rate = 0.00370 M2s [NO2(2)] [C2el*
Rate = 0.0712 M's[NO2] [Cl2(g)]
Transcribed Image Text:12 Note: This is a 2 point question. The reaction below is first order with respect to NO and second order with respect to Cl, Determine the value of the rate constant and write the rate law. 14 15 2 NO + Cl2 (e) (2) → 2 NOCI (e) Initial [NO] Initial [Cl] Initial Rate (M/s) 18 Experiment 0.0255 -- 0.0125 M 2. 0.0125 M 0.0510 21 0.0250 M 0.0255 4.55 x 10-5 3. Rate = 0.00370 M2s- [NOe]? [Clze] to O Rate = 2.79 M25- [NO)] [Clze]! Rate = 0.0712 M's'[NO2] [Cl} O Rate = 5.70 M's' [NO2]' [Cll² Rate = 5.70 M²²s²1 [NO]² [Cly«]' %3D Rate = 2.79 M2s1 [NO]' [C»el° Rate = 0.00370 M2s [NO2(2)] [C2el* Rate = 0.0712 M's[NO2] [Cl2(g)]
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