e) Using your answers to part c and d, draw the reaction co-ordinate diagram for the Diels-Alder reaction shown above. Which product do you expect to be favored at high temperatures, and which product at low temperatures (which product is the kinetic product and which one the thermodynamic product)? 3. Consider the following Diels-Alder reaction: a) Draw a detailed mechanism for the reaction and show the structures of the endo and exo products. b) Label the endo and exo product in part a. c) Which transition state is lower in energy, the one leading to the exo product or the one leading to the endo product? d) Which product do you expect to be more stable (the exo or the endo product) and why?
e) Using your answers to part c and d, draw the reaction co-ordinate diagram for the Diels-Alder reaction shown above. Which product do you expect to be favored at high temperatures, and which product at low temperatures (which product is the kinetic product and which one the thermodynamic product)? 3. Consider the following Diels-Alder reaction: a) Draw a detailed mechanism for the reaction and show the structures of the endo and exo products. b) Label the endo and exo product in part a. c) Which transition state is lower in energy, the one leading to the exo product or the one leading to the endo product? d) Which product do you expect to be more stable (the exo or the endo product) and why?
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter14: Elimination
Section: Chapter Questions
Problem 22E
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