Chlorine can be prepared in the laboratory by the reaction of manganese dioxide with hydrochloric acid, HC1(aq), asdescribed by the chemical equationMnO,(s) + 4 HC1(aq)MnCl, (aq) + 2 H,O(1) + Cl,(g)How much MnO, (s) should be added to excess HC1(aq) to obtain 175 mL Cl, (g) at 25 °C and 775 Torr?mass of MnO,:

Given,Volume of Cl2 gas, V = 175 mL = 0.175 L (1 mL = 0.001 L)Temperature, T = 25 °C = (25 + 273)…

Answered: Chlorine can be prepared in the…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter4: Chemical Reactions In Solution

Section: Chapter Questions

Problem 4.115QE

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Determine the volume of sodium hydroxide solution needed to prepare 26.2 g sodium phosphate, Na3PO4, by the reaction 3NaOH(aq)+H3PO4(aq)Na3PO4(aq)+3H2O(l) The sodium hydroxide solution, whose density is 1.133 g/mL, contains 12.0% NaOH by mass.
A student wants to prepare 1.00 L of a 1.00-M solution of NaOH (molar mass = 40.00 g/mol). If solid NaOH is available, how would the student prepare this solution? If 2.00 M NaOH is available, how would the student prepare the solution? To help ensure three significant figures in the NaOH molarity, to how many significant figures should the volumes and mass be determined?
You are given a solid mixture of NaNO2 and NaCl and are asked to analyze it for the amount of NaNO2 present. To do so, you allow the mixture to react with sulfamic acid, HSO3NH2, in water according to the equation NaNO2(aq) + HSO3NH2(aq) NaHSO4(aq) + H2O() + N2(g) What is the weight percentage of NaNO2 in 1.232 g of the solid mixture if reaction with sulfa-mic acid produces 295 mL of dry N2 gas with a pressure of 713 mm Hg at 21.0 C?
A soluble iodide was dissolved in water. Then an excess of silver nitrate, AgNO3, was added to precipitate all of the iodide ion as silver iodide, AgI. If 1.545 g of the soluble iodide gave 2.185 g of silver iodide, how many grams of iodine are in the sample of soluble iodide? What is the mass percentage of iodine, I, in the compound?
You want to prepare a 1.0 mol/kg solution of ethyleneglycol, C2H4(OH)2, in water. Calculate the mass of ethylene glycol you would need to mix with 950. g water.
A student weighs out a 4.80-g sample of aluminum bromide, transfers it to a 100-mL volumetric flask, adds enough water to dissolve it, and then adds water to the 100-mL mark. What is the molarity of aluminum bromide in the resulting solution?
On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?
The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.
Determine the volume of sulfuric acid solution needed to prepare 37.4 g of aluminum sulfate, Al2(SO4)3, by the reaction 2Al(s)+3H2SO4(aq)Al2(SO4)3(aq)+3H2(g) The sulfuric acid solution, whose density is 1.104 g/mL, contains 15.0% H2SO4 by mass.
A soft drink contains an unknown mass of citric acid, C3H5O(COOH)3. It requires 6.42 mL of 9.580 × 10−2-M NaOH to neutralize the citric acid in 10.0 mL of the soft drink. C3H5O(COOH)3(aq) + 3 NaOH(aq) → Na3C3H5O(COO)3(aq) + 3 H2O(ℓ) Determine which step in these calculations for the mass of citric acid in 1 mL soft drink is incorrect? Why? n (NaOH) = (6.42 mL)(1L/1000 mL)(9.580 × 10−2 mol/L) n (citric acid) = (6.15 × 10−4 mol NaOH) × (3 mol citric acid/1 mol NaOH) m (citric acid in sample) = (1.85 × 10−3 mol citric acid) × (192.12 g/mol citric acid) m (citric acid in 1 mL soft drink) = (0.354 g citric acid)/(10 mL soft drink) Determine the correct result.
Acetic acid (HC2H3O2) can be prepared by the action of the acetobacter organism on dilute solutions of ethanol (C2H5OH). The equation for the reaction is C2H5OH(aq)+O2(g)HC2H3O2(aq)+H2OHow many milliliters of a 12.5% (by volume) solution of ethanol are required to produce 175 mL of 0.664 M acetic acid? (Densityofpureethanol=0.789g/mL.)

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