Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect CH3 1. Inductive effect Resonance effect 2. -P(CH3)3 trimethylphosphonium 3. --NHCH₂CH₂CH₂C=N; Inductive effect Inductive effect Resonance effect Resonance effect

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.7: Sigmatropic Rearrangements
Problem 7P
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Classify the following substituents according to whether they are electron donors or electron acceptors
relative to hydrogen by the resonance and the inductive mechanisms.
a = acceptor
d = donor
n = no effect
CH3
1.
Inductive effect
Resonance effect
2.
-P(CH3)3
trimethylphosphonium
3. NHCH₂CH₂CH₂C=N;
Inductive effect
Inductive effect
Resonance effect
Resonance effect
Transcribed Image Text:Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect CH3 1. Inductive effect Resonance effect 2. -P(CH3)3 trimethylphosphonium 3. NHCH₂CH₂CH₂C=N; Inductive effect Inductive effect Resonance effect Resonance effect
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