Consider the following data on the hypothetical reaction 2A + 2B C + 3D between reactants A and B to give products: Sl No. [A] (mold m-3 ) [B] (mold m-3 ) Rate, r (mold m-3 s -1 ) i 6.0 × 10-3 1.0 × 10-3 0.012 ii 6.0 × 10-3 2.0 × 10-3 0.024 iii 2.0 × 10-3 1.5 × 10-3 0.002 iv 4.0 × 10-3 1.5 × 10-3 0.008 If the reaction rate is given by r = [A]a [B]b , then (i) what is the order of the reaction with respect to A? (ii) what is the order of the reaction with respect to B? (iii) what is the overall order? (iv) Write the rate law equation. (v) Calculate the rate constant.

Principles of Instrumental Analysis
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Chapter2: Electrical Components And Circuits
Section: Chapter Questions
Problem 2.4QAP
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Consider the following data on the hypothetical reaction 2A + 2B C + 3D between reactants A and B to
give products:
Sl No. [A] (mold m-3
) [B] (mold m-3
) Rate, r (mold m-3
s
-1
)
i 6.0 × 10-3 1.0 × 10-3 0.012
ii 6.0 × 10-3 2.0 × 10-3 0.024
iii 2.0 × 10-3 1.5 × 10-3 0.002
iv 4.0 × 10-3 1.5 × 10-3 0.008
If the reaction rate is given by r = [A]a
[B]b
, then (i) what is the order of the reaction with respect to A? (ii)
what is the order of the reaction with respect to B? (iii) what is the overall order? (iv) Write the rate law
equation. (v) Calculate the rate constant.

8. Consider the following data on the hypothetical reaction 2A + 2B C+ 3D between reactants A and B to
give products:
SI No.
[A] (mold m³)
[B] (mold m³)
Rate, r (mold m s')
i
6.0 x 103
1.0 x 103
0.012
ii
6.0 x 103
2.0 x 103
0.024
iii
2.0 x 103
1.5 x 10*
0.002
iv
4.0 x 103
1.5 x 103
0.008
If the reaction rate is given by r = [A]°[B]', then (î) what is the order of the reaction with respect to A? (ii)
what is the order of the reaction with respect to B? (iii) what is the overall order? (iv) Write the rate law
equation. (v) Calculate the rate constant. [4]
Transcribed Image Text:8. Consider the following data on the hypothetical reaction 2A + 2B C+ 3D between reactants A and B to give products: SI No. [A] (mold m³) [B] (mold m³) Rate, r (mold m s') i 6.0 x 103 1.0 x 103 0.012 ii 6.0 x 103 2.0 x 103 0.024 iii 2.0 x 103 1.5 x 10* 0.002 iv 4.0 x 103 1.5 x 103 0.008 If the reaction rate is given by r = [A]°[B]', then (î) what is the order of the reaction with respect to A? (ii) what is the order of the reaction with respect to B? (iii) what is the overall order? (iv) Write the rate law equation. (v) Calculate the rate constant. [4]
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