4) The esterification reaction between butanol and acetic acid in the presence of sulfuric acid is carried out in a constant volume batch reactor at 25°C. Excess butanol is used. The initial concentration of butanol is 50 mol/dm3. H2SO II C4H9-O-C-CH3+ H2O CH3COOH+C4H9OH (A) (B) (C) (D) a) Using the following data find the reaction order with respect to acetic acid. 10 20 30 40 50 60 Time(min) Concentration of Acetic Acid 3.38 2.45 1.74 1.23 0.88 0.62 0.44 (mol/dm3) b) In a separate set of experiments, the reaction order with respect to butanol was found to be first order. Determine the reaction rate constant.

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4)
The esterification reaction between butanol and acetic acid in the presence of
sulfuric acid is carried out in a constant volume batch reactor at 25°C. Excess
butanol is used. The initial concentration of butanol is 50 mol/dm3.
H2SO,
II
САНо-О-С-СНз+ Н2О
CH;COOH+C.H9OH
(A)
(B)
(C)
(D)
a) Using the following data find the reaction order with respect to acetic acid.
0.
10
20
30
40
50
60
Time(min)
Concentration of
Acetic Acid
(mol/dm³)
3.38
2.45
1.74
1.23
0,88
0.62
0.44
b) In a separate set of experiments, the reaction order with respect to butanol
was found to be first order. Determine the reaction rate constant.
Transcribed Image Text:4) The esterification reaction between butanol and acetic acid in the presence of sulfuric acid is carried out in a constant volume batch reactor at 25°C. Excess butanol is used. The initial concentration of butanol is 50 mol/dm3. H2SO, II САНо-О-С-СНз+ Н2О CH;COOH+C.H9OH (A) (B) (C) (D) a) Using the following data find the reaction order with respect to acetic acid. 0. 10 20 30 40 50 60 Time(min) Concentration of Acetic Acid (mol/dm³) 3.38 2.45 1.74 1.23 0,88 0.62 0.44 b) In a separate set of experiments, the reaction order with respect to butanol was found to be first order. Determine the reaction rate constant.
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