Consider the molecule and its rotational energy diagram. Note that the tert-butyl (tBu) group s the largest group. Br Molecule for Q14 Rotational Coordinate a. Complete the Newman projection to show the molecule in its lowest energy conformation (D). F b. Complete the Newman projection to show the molecule in its highest energy conformation (A). F c. Which group is eclipsed with the tBu group at position E in the energy diagram? d. What is the dihedral angle for the Br-C-C plane and the tBu-C-C plane at position F in the energy diagram?

Organic Chemistry: A Guided Inquiry
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ISBN:9780618974122
Author:Andrei Straumanis
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Chapter17: Conjugation And Molecular Orbital (mo) Theory
Section: Chapter Questions
Problem 19CTQ
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Consider the molecule and its rotational energy diagram. Note that the tert-butyl (tBu) group
is the largest group.
A
Br
B
Molecule for Q14
Rotational Coordinate
a. Complete the Newman projection to show the molecule in its lowest energy
conformation (D).
F
b. Complete the Newman projection to show the molecule in its highest energy
conformation (A).
F
c. Which group is eclipsed with the tBu group at position E in the energy diagram?
d. What is the dihedral angle for the Br-C-C plane and the tBu-C-C plane at position F in
the energy diagram?
Energy
Transcribed Image Text:Consider the molecule and its rotational energy diagram. Note that the tert-butyl (tBu) group is the largest group. A Br B Molecule for Q14 Rotational Coordinate a. Complete the Newman projection to show the molecule in its lowest energy conformation (D). F b. Complete the Newman projection to show the molecule in its highest energy conformation (A). F c. Which group is eclipsed with the tBu group at position E in the energy diagram? d. What is the dihedral angle for the Br-C-C plane and the tBu-C-C plane at position F in the energy diagram? Energy
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