Cu(OAc)2 (10 mol%) NazS203 (2 equiv.) CO2ET + KS OEt DMSO, 110 °c Ph H3C S=0--1---I H3C %3D Cu(OAc)2 (10 mol%) ACOH (2 equiv.) C-T complex A DMF, 110 °C B.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.14QAP
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Find products A and B with a proper mechanism.

Cu(OAc)2 (10 mol%)
Na,S203 (2 equiv.)
-CO2ET
+ KS
В
OEt
DMSO, 110 °c
Ph
H3C
S=0--I---I
H3C
Cu(OAc)2 (10 mol%)
ACOH (2 equiv.)
C-T complex
A
DMF, 110 °C
Transcribed Image Text:Cu(OAc)2 (10 mol%) Na,S203 (2 equiv.) -CO2ET + KS В OEt DMSO, 110 °c Ph H3C S=0--I---I H3C Cu(OAc)2 (10 mol%) ACOH (2 equiv.) C-T complex A DMF, 110 °C
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