The two structures for Iron - penta - carbonyl: Ço "Fe" oc co oc-FeCO co čo (A) (B) .Structure A has a rCO = 2A1 + B1 + E .Structure B has a rCO = 2A’1 + E' + A"2 The IR spectrum of Fe(CO)5 gave 3 different CO stretches at 1521 cm-1, 1548 cm-1 and 1732 cm-1 1. What of the 2 structures is observed and why that structure? and what could be seen of this compound in a raman spectro?

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter1: Introduction
Section: Chapter Questions
Problem 1.11QAP
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The two structures for Iron - penta - carbonyl:
Ço
OC.
oc-Fe"
oc
co
(A)
(B)
.Structure A has a rCO = 2A1 + B1 + E
.Structure B has a rCO = 2A'1+ E' + A"2
The IR spectrum of Fe(CO)5 gave 3 different
CO stretches at 1521 cm-1, 1548 cm-1 and
1732 cm-1
1. What of the 2 structures is observed and
why that structure?
and what could be seen of this compound in
a raman spectro?
Transcribed Image Text:The two structures for Iron - penta - carbonyl: Ço OC. oc-Fe" oc co (A) (B) .Structure A has a rCO = 2A1 + B1 + E .Structure B has a rCO = 2A'1+ E' + A"2 The IR spectrum of Fe(CO)5 gave 3 different CO stretches at 1521 cm-1, 1548 cm-1 and 1732 cm-1 1. What of the 2 structures is observed and why that structure? and what could be seen of this compound in a raman spectro?
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