Еxperiment [A], (M) [B], (M) Rate (M/s) 1 0.0100 0.100 1.0 × 10¬03 2 0.0300 0.100 3.0 × 10–03 3 0.0300 0.300 2.7 × 10¬02 a) Determine the rate law for this reaction. b) Calculate the rate constant. c) Calculate the rate when [A] 0.200 M and [B] 0.200 M.

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Chapter12: Chemical Kinetics
Section: Chapter Questions
Problem 3RQ: One experimental procedure that can be used to determine the rate law of a reaction is the method of...
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Еxperiment
[A]o (M)
[B], (M)
Rate (M/s)
1
0.0100
0.100
1.0 X 10-03
0.0300
0.100
3.0 × 10–03
0.0300
0.300
2.7 × 10–02
a) Determine the rate law for this reaction.
b) Calculate the rate constant.
c) Calculate the rate when [A] 0.200 M and [B] 0.200 M.
6. A reaction of the form aA → Products is second order with a half-life of 425 s. What is the rate constant of the
reaction if the initial concentration of A is 5.99 x 10° mol/L?
7. The following values of the rate constant were obtained for the decomposition of nitrogen dioxide at various
temperatures. Plot the logarithm of k versus 1/T and from the graph obtain the energy of activation.
Тетрerature ( C)
k (L/mol s)
320
0.527
330
0.776
340
1.121
350
1.607
Topic: Nuclear chemistry
8. Complete the following nuclear reactions.
a. Si
b. STi + ?
ISP + ?
>
44
22
44
--
21
142-
56
252,
C. 98CF
Ba + ? + 4on
>
9. Consider Rn-222
a. Predict the type of radioactive decay that Rn-222 is most likely to undergo.
b. Write the equation for the decay process.
c. The half-life of Rn-222 is 3.82 days. If you start with a 150.0-g sample of Rn-222, how much remains after
15.0 days?
Transcribed Image Text:Еxperiment [A]o (M) [B], (M) Rate (M/s) 1 0.0100 0.100 1.0 X 10-03 0.0300 0.100 3.0 × 10–03 0.0300 0.300 2.7 × 10–02 a) Determine the rate law for this reaction. b) Calculate the rate constant. c) Calculate the rate when [A] 0.200 M and [B] 0.200 M. 6. A reaction of the form aA → Products is second order with a half-life of 425 s. What is the rate constant of the reaction if the initial concentration of A is 5.99 x 10° mol/L? 7. The following values of the rate constant were obtained for the decomposition of nitrogen dioxide at various temperatures. Plot the logarithm of k versus 1/T and from the graph obtain the energy of activation. Тетрerature ( C) k (L/mol s) 320 0.527 330 0.776 340 1.121 350 1.607 Topic: Nuclear chemistry 8. Complete the following nuclear reactions. a. Si b. STi + ? ISP + ? > 44 22 44 -- 21 142- 56 252, C. 98CF Ba + ? + 4on > 9. Consider Rn-222 a. Predict the type of radioactive decay that Rn-222 is most likely to undergo. b. Write the equation for the decay process. c. The half-life of Rn-222 is 3.82 days. If you start with a 150.0-g sample of Rn-222, how much remains after 15.0 days?
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