Follow the detailed instructions provided in each of the subsections (a-b): a) Draw the structure of the product (3) obtained by reacting 2,4-pentadione 1 with the a,ß- unsaturated ketone 2 under basic conditions. Using curly arrows, draw the mechanism of the reaction. 1. NACEL. EtCH CH:603 2. H:O 1 3 b) Using the Evan's pKa table, assign the pKa of 2,4-pentadione (1) and anilinium ion (4) in water. Will the equilibrium of this reaction lie towards the products or towards the starting materials? Explain your reasoning NH2 NH: or 2 3 4

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter21: Nas: Nucleophilic Aromatic Substitution
Section: Chapter Questions
Problem 7E
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Follow the detailed instructions provided in each of the subsections (a-b):
a) Draw the structure of the product (3) obtained by reacting 2,4-pentadione 1 with the a,ß-
unsaturated ketone 2 under basic conditions. Using curly arrows, draw the mechanism of
the reaction.
1. NACET. ELCH
2. H:o
b) Using the Evan's pka table, assign the pKa of 2,4-pentadione (1) and anilinium ion (4) in
water.
Will the equilibrium of this reaction lie towards the products or towards the starting
materials? Explain your reasoning
NH2
NH:
or
3
4
Transcribed Image Text:Follow the detailed instructions provided in each of the subsections (a-b): a) Draw the structure of the product (3) obtained by reacting 2,4-pentadione 1 with the a,ß- unsaturated ketone 2 under basic conditions. Using curly arrows, draw the mechanism of the reaction. 1. NACET. ELCH 2. H:o b) Using the Evan's pka table, assign the pKa of 2,4-pentadione (1) and anilinium ion (4) in water. Will the equilibrium of this reaction lie towards the products or towards the starting materials? Explain your reasoning NH2 NH: or 3 4
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