For each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S, or leave S unchanged. If you don't have enough information to decide, check the "not enough information" button in the last column. Note for advanced students: you may assume ideal gas and ideal solution behaviour. System Change AS O AS <0 300 mL of a solution made from 0.5 g of NH Cl crystallizes out of O AS = 0 ammonium chloride (NH Cl) the solution, without changing the temperature. O AS> 0 dissolved in water. not enough information O AS <0 A solution made of ammonium O As = 0 chloride (NH,CI) in water, at 50. mL of pure water is added to the solution. O AS> 0 27°C. not enough O information O AS < 0 20. L of pure carbon dioxide (CO,) O AS = 0 The gases are mixed, with the gas and 20.0 L of pure helium (He) pressure kept constant at 3 atm. O As > 0 not enough O information gas, both at 3 atm and -20°C.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter4: Gibbs Energy And Chemical Potential
Section: Chapter Questions
Problem 4.1E: List the sets of conditions that allow dS, dU, and dH of a process in a system act as a spontaneity...
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For each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S
of the system, decrease S, or leave S unchanged. If you don't have enough information to decide, check the "not enough information" button in the last column.
Note for advanced students: you may assume ideal gas and ideal solution behaviour.
System
Change
AS
O AS < 0
300 mL of a solution made from
0.5 g of NH Cl crystallizes out of
O AS = 0
ammonium chloride (NH,Cl)
the solution, without changing the
temperature.
O AS > 0
dissolved in water.
not enough
information
AS < 0
A solution made of ammonium
O AS = 0
chloride (NH, CI) in water, at
50. mL of pure water is added to
the solution.
AS > 0
27° C.
not enough
information
O AS < 0
20. L of pure carbon dioxide (CO,)
O AS = 0
The gases are mixed, with the
gas and 20.0L of pure helium (He)
pressure kept constant at 3 atm.
O AS > 0
gas, both at 3 atm and -20°C.
not enough
information
Transcribed Image Text:For each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S, or leave S unchanged. If you don't have enough information to decide, check the "not enough information" button in the last column. Note for advanced students: you may assume ideal gas and ideal solution behaviour. System Change AS O AS < 0 300 mL of a solution made from 0.5 g of NH Cl crystallizes out of O AS = 0 ammonium chloride (NH,Cl) the solution, without changing the temperature. O AS > 0 dissolved in water. not enough information AS < 0 A solution made of ammonium O AS = 0 chloride (NH, CI) in water, at 50. mL of pure water is added to the solution. AS > 0 27° C. not enough information O AS < 0 20. L of pure carbon dioxide (CO,) O AS = 0 The gases are mixed, with the gas and 20.0L of pure helium (He) pressure kept constant at 3 atm. O AS > 0 gas, both at 3 atm and -20°C. not enough information
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