For the proposed reaction mechanism shown below what is the overall chemical equation predicted by this mechanism and what is the rate law derived from this mechanism? Hint The slow step determines the overall rate then see if there is a possible substitution for one of the reactant. When you get to the equilibrium reaction write the rate law in terms of [N,Og] and then substitute this back into the overall rate equation. (slow step, K1 N205 - NO2 + NO3 forward rate) (fast step, K2 NO2 + NO3 - NO2 + O2 + NO forward rate) (fast step. equilibrium, K3 NO + N2O5 - 3NO2 forward rate, K.a reverse rate)
For the proposed reaction mechanism shown below what is the overall chemical equation predicted by this mechanism and what is the rate law derived from this mechanism? Hint The slow step determines the overall rate then see if there is a possible substitution for one of the reactant. When you get to the equilibrium reaction write the rate law in terms of [N,Og] and then substitute this back into the overall rate equation. (slow step, K1 N205 - NO2 + NO3 forward rate) (fast step, K2 NO2 + NO3 - NO2 + O2 + NO forward rate) (fast step. equilibrium, K3 NO + N2O5 - 3NO2 forward rate, K.a reverse rate)
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
Section: Chapter Questions
Problem 20.75E: A proposed mechanism for the gas-phase chlorination of methane is...
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