For the proposed reaction mechanism shown below what is the overall chemical equation predicted by this mechanism and what is the rate law derived from this mechanism? Hint The slow step determines the overall rate then see if there is a possible substitution for one of the reactant. When you get to the equilibrium reaction write the rate law in terms of [N,Og] and then substitute this back into the overall rate equation. (slow step, K1 N205 - NO2 + NO3 forward rate) (fast step, K2 NO2 + NO3 - NO2 + O2 + NO forward rate) (fast step. equilibrium, K3 NO + N2O5 - 3NO2 forward rate, K.a reverse rate)

Physical Chemistry
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Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
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Problem 20.75E: A proposed mechanism for the gas-phase chlorination of methane is...
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For the proposed reaction mechanism shown below what is the overall chemical equation predicted
by this mechanism and what is the rate law derived from this mechanism? Hint The slow step
determines the overall rate then see if there is a possible substitution for one of the reactant.
When you get to the equilibrium reaction write the rate law in terms of [N,Og] and then substitute
this back into the overall rate equation.
(slow step
N205
NO2 + NO3
forward
rate)
(fast step
NO2 + NO3 - NO, + 0, + NO
forward
rate)
(fast step
equil.brium.
K3
forward
rate K3
NO + N2O5
3NO2
reverse
rate)
Transcribed Image Text:For the proposed reaction mechanism shown below what is the overall chemical equation predicted by this mechanism and what is the rate law derived from this mechanism? Hint The slow step determines the overall rate then see if there is a possible substitution for one of the reactant. When you get to the equilibrium reaction write the rate law in terms of [N,Og] and then substitute this back into the overall rate equation. (slow step N205 NO2 + NO3 forward rate) (fast step NO2 + NO3 - NO, + 0, + NO forward rate) (fast step equil.brium. K3 forward rate K3 NO + N2O5 3NO2 reverse rate)
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