For the proposed reaction mechanism shown below what is the overall chemical equation predicted by this mechanism and what is the rate law derived from this mechanism? Hint: The slow step determines the overall rate then see if there is a possible substitution for one of the reactant. When you get to the equilibrium reaction write the rate law in terms of [N2O5] and then substitute this back into the overall rate equation. (slow step, K1 N205 → NO2 + NO3 forward rate) (fast step, K2 forward rate) NO2 + NO3 → NO2 + O2 + NO (fast step, equilibrium, K3 forward rate, K3 = NO + N205 → 3NO2
For the proposed reaction mechanism shown below what is the overall chemical equation predicted by this mechanism and what is the rate law derived from this mechanism? Hint: The slow step determines the overall rate then see if there is a possible substitution for one of the reactant. When you get to the equilibrium reaction write the rate law in terms of [N2O5] and then substitute this back into the overall rate equation. (slow step, K1 N205 → NO2 + NO3 forward rate) (fast step, K2 forward rate) NO2 + NO3 → NO2 + O2 + NO (fast step, equilibrium, K3 forward rate, K3 = NO + N205 → 3NO2
Chapter12: Chemical Kinetics
Section: Chapter Questions
Problem 3RQ: One experimental procedure that can be used to determine the rate law of a reaction is the method of...
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